TY - JOUR
T1 - [1,5]Sigmatropic shift of hydrogen in amination of 3-pyrrolidino-1,2,4- triazine 4-oxide
AU - Chupakhin, Oleg N.
AU - Kozhevnikov, Valery N.
AU - Kozhevnikov, Dmitry N.
AU - Rusinov, Vladimir L.
PY - 1999/8/13
Y1 - 1999/8/13
N2 - The reaction of 3-pyrrolidino-1,2,4-triazine 4-oxide with ammonia leads to the product of tele-substitution of pyrrolidine - 5-amino-1,2,4-triazine 4-oxide. Sigmatropic shift of hydrogen postulated for such reactions has been proved by isolation of key intermediates.
AB - The reaction of 3-pyrrolidino-1,2,4-triazine 4-oxide with ammonia leads to the product of tele-substitution of pyrrolidine - 5-amino-1,2,4-triazine 4-oxide. Sigmatropic shift of hydrogen postulated for such reactions has been proved by isolation of key intermediates.
UR - http://www.scopus.com/inward/record.url?scp=0033551823&partnerID=8YFLogxK
U2 - 10.1016/S0040-4039(99)01211-3
DO - 10.1016/S0040-4039(99)01211-3
M3 - Article
AN - SCOPUS:0033551823
SN - 0040-4039
VL - 40
SP - 6099
EP - 6100
JO - Tetrahedron Letters
JF - Tetrahedron Letters
IS - 33
ER -