[1,5]Sigmatropic shift of hydrogen in amination of 3-pyrrolidino-1,2,4- triazine 4-oxide

Oleg N. Chupakhin; Valery N. Kozhevnikov; Dmitry N. Kozhevnikov; Vladimir L. Rusinov

doi:10.1016/S0040-4039(99)01211-3

[1,5]Sigmatropic shift of hydrogen in amination of 3-pyrrolidino-1,2,4- triazine 4-oxide

Oleg N. Chupakhin^*, Valery N. Kozhevnikov^*, Dmitry N. Kozhevnikov^*, Vladimir L. Rusinov^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

The reaction of 3-pyrrolidino-1,2,4-triazine 4-oxide with ammonia leads to the product of tele-substitution of pyrrolidine - 5-amino-1,2,4-triazine 4-oxide. Sigmatropic shift of hydrogen postulated for such reactions has been proved by isolation of key intermediates.

Original language	English
Pages (from-to)	6099-6100
Number of pages	2
Journal	Tetrahedron Letters
Volume	40
Issue number	33
DOIs	https://doi.org/10.1016/S0040-4039(99)01211-3
Publication status	Published - 13 Aug 1999
Externally published	Yes

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10.1016/S0040-4039(99)01211-3

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title = "[1,5]Sigmatropic shift of hydrogen in amination of 3-pyrrolidino-1,2,4- triazine 4-oxide",

abstract = "The reaction of 3-pyrrolidino-1,2,4-triazine 4-oxide with ammonia leads to the product of tele-substitution of pyrrolidine - 5-amino-1,2,4-triazine 4-oxide. Sigmatropic shift of hydrogen postulated for such reactions has been proved by isolation of key intermediates.",

author = "Chupakhin, \{Oleg N.\} and Kozhevnikov, \{Valery N.\} and Kozhevnikov, \{Dmitry N.\} and Rusinov, \{Vladimir L.\}",

year = "1999",

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doi = "10.1016/S0040-4039(99)01211-3",

language = "English",

volume = "40",

pages = "6099--6100",

journal = "Tetrahedron Letters",

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T1 - [1,5]Sigmatropic shift of hydrogen in amination of 3-pyrrolidino-1,2,4- triazine 4-oxide

AU - Chupakhin, Oleg N.

AU - Kozhevnikov, Valery N.

AU - Kozhevnikov, Dmitry N.

AU - Rusinov, Vladimir L.

PY - 1999/8/13

Y1 - 1999/8/13

N2 - The reaction of 3-pyrrolidino-1,2,4-triazine 4-oxide with ammonia leads to the product of tele-substitution of pyrrolidine - 5-amino-1,2,4-triazine 4-oxide. Sigmatropic shift of hydrogen postulated for such reactions has been proved by isolation of key intermediates.

AB - The reaction of 3-pyrrolidino-1,2,4-triazine 4-oxide with ammonia leads to the product of tele-substitution of pyrrolidine - 5-amino-1,2,4-triazine 4-oxide. Sigmatropic shift of hydrogen postulated for such reactions has been proved by isolation of key intermediates.

UR - https://www.scopus.com/pages/publications/0033551823

U2 - 10.1016/S0040-4039(99)01211-3

DO - 10.1016/S0040-4039(99)01211-3

M3 - Article

AN - SCOPUS:0033551823

SN - 0040-4039

VL - 40

SP - 6099

EP - 6100

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 33

ER -

[1,5]Sigmatropic shift of hydrogen in amination of 3-pyrrolidino-1,2,4- triazine 4-oxide

Abstract

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