Alkane hydroxylation reactions catalysed by binuclear manganese and iron complexes

David Tetard; Jean Baptiste Verlhac

doi:10.1016/S1381-1169(97)80001-5

Alkane hydroxylation reactions catalysed by binuclear manganese and iron complexes

David Tetard, Jean Baptiste Verlhac^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

Binuclear manganese(III/IV) or iron(III/III) complexes efficiently functionalize cyclohexane using hydroperoxides or peracids as oxidants. A mechanistic study clearly demonstrate the role of dioxygen gas in these hydroxylatiom reactions. Moreover, it was demonstrated that the cleavage of the peroxy bond occurred mainly by homolysis.

Original language	English
Pages (from-to)	223-230
Number of pages	8
Journal	Journal of Molecular Catalysis A: Chemical
Volume	113
Issue number	1-2
DOIs	https://doi.org/10.1016/S1381-1169(97)80001-5
Publication status	Published - 25 Nov 1996
Externally published	Yes

Keywords

Alkane hydroxylation
Hydroperoxyde
Iron complex
Manganese complex
Peracid

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10.1016/S1381-1169(97)80001-5

Cite this

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title = "Alkane hydroxylation reactions catalysed by binuclear manganese and iron complexes",

abstract = "Binuclear manganese(III/IV) or iron(III/III) complexes efficiently functionalize cyclohexane using hydroperoxides or peracids as oxidants. A mechanistic study clearly demonstrate the role of dioxygen gas in these hydroxylatiom reactions. Moreover, it was demonstrated that the cleavage of the peroxy bond occurred mainly by homolysis.",

keywords = "Alkane hydroxylation, Hydroperoxyde, Iron complex, Manganese complex, Peracid",

author = "David Tetard and Verlhac, \{Jean Baptiste\}",

note = "Funding Information: We are indebted to Elf-Aquitaine for financial support.",

year = "1996",

month = nov,

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doi = "10.1016/S1381-1169(97)80001-5",

language = "English",

volume = "113",

pages = "223--230",

journal = "Journal of Molecular Catalysis A: Chemical",

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T1 - Alkane hydroxylation reactions catalysed by binuclear manganese and iron complexes

AU - Tetard, David

AU - Verlhac, Jean Baptiste

N1 - Funding Information: We are indebted to Elf-Aquitaine for financial support.

PY - 1996/11/25

Y1 - 1996/11/25

N2 - Binuclear manganese(III/IV) or iron(III/III) complexes efficiently functionalize cyclohexane using hydroperoxides or peracids as oxidants. A mechanistic study clearly demonstrate the role of dioxygen gas in these hydroxylatiom reactions. Moreover, it was demonstrated that the cleavage of the peroxy bond occurred mainly by homolysis.

AB - Binuclear manganese(III/IV) or iron(III/III) complexes efficiently functionalize cyclohexane using hydroperoxides or peracids as oxidants. A mechanistic study clearly demonstrate the role of dioxygen gas in these hydroxylatiom reactions. Moreover, it was demonstrated that the cleavage of the peroxy bond occurred mainly by homolysis.

KW - Alkane hydroxylation

KW - Hydroperoxyde

KW - Iron complex

KW - Manganese complex

KW - Peracid

UR - https://www.scopus.com/pages/publications/0030602075

U2 - 10.1016/S1381-1169(97)80001-5

DO - 10.1016/S1381-1169(97)80001-5

M3 - Article

AN - SCOPUS:0030602075

SN - 1381-1169

VL - 113

SP - 223

EP - 230

JO - Journal of Molecular Catalysis A: Chemical

JF - Journal of Molecular Catalysis A: Chemical

IS - 1-2

ER -

Alkane hydroxylation reactions catalysed by binuclear manganese and iron complexes

Abstract

Keywords

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