An unusual ready inversion of sp3 skeletal carbon in an organometallic complex

Jonathan Bookham

doi:10.1016/S1387-7003(98)00083-5

An unusual ready inversion of sp3 skeletal carbon in an organometallic complex

Jonathan Bookham

Applied Sciences Department

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Quantitative inversion at the chiral sp3 hybridised carbon atoms in the octahedral tetracarbonyl tungsten(0) chelate complex of the C2 chiral diphosphine Ph2PCHArCHArPPh2 (Ar=2-pyridyl) occurs at moderately elevated temperatures.

Original language	English
Pages (from-to)	309-313
Journal	Inorganic Chemistry Communications
Volume	1
Issue number	8
DOIs	https://doi.org/10.1016/S1387-7003(98)00083-5
Publication status	Published - Aug 1998

Keywords

Carbonyl complexes
Diphosphine complexes
Inversion
Tungsten complexes

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10.1016/S1387-7003(98)00083-5

http://www.sciencedirect.com/science/article/pii/S1387700398000835

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title = "An unusual ready inversion of sp3 skeletal carbon in an organometallic complex",

abstract = "Quantitative inversion at the chiral sp3 hybridised carbon atoms in the octahedral tetracarbonyl tungsten(0) chelate complex of the C2 chiral diphosphine Ph2PCHArCHArPPh2 (Ar=2-pyridyl) occurs at moderately elevated temperatures.",

keywords = "Carbonyl complexes, Diphosphine complexes, Inversion, Tungsten complexes",

author = "Jonathan Bookham",

year = "1998",

month = aug,

doi = "10.1016/S1387-7003(98)00083-5",

language = "English",

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journal = "Inorganic Chemistry Communications",

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publisher = "Elsevier",

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T1 - An unusual ready inversion of sp3 skeletal carbon in an organometallic complex

AU - Bookham, Jonathan

PY - 1998/8

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N2 - Quantitative inversion at the chiral sp3 hybridised carbon atoms in the octahedral tetracarbonyl tungsten(0) chelate complex of the C2 chiral diphosphine Ph2PCHArCHArPPh2 (Ar=2-pyridyl) occurs at moderately elevated temperatures.

AB - Quantitative inversion at the chiral sp3 hybridised carbon atoms in the octahedral tetracarbonyl tungsten(0) chelate complex of the C2 chiral diphosphine Ph2PCHArCHArPPh2 (Ar=2-pyridyl) occurs at moderately elevated temperatures.

KW - Carbonyl complexes

KW - Diphosphine complexes

KW - Inversion

KW - Tungsten complexes

U2 - 10.1016/S1387-7003(98)00083-5

DO - 10.1016/S1387-7003(98)00083-5

M3 - Article

SN - 1387-7003

VL - 1

SP - 309

EP - 313

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 8

ER -

An unusual ready inversion of sp3 skeletal carbon in an organometallic complex

Abstract

Keywords

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