An unusual ready inversion of sp3 skeletal carbon in an organometallic complex

Jonathan Bookham

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

Quantitative inversion at the chiral sp3 hybridised carbon atoms in the octahedral tetracarbonyl tungsten(0) chelate complex of the C2 chiral diphosphine Ph2PCHArCHArPPh2 (Ar=2-pyridyl) occurs at moderately elevated temperatures.
Original languageEnglish
Pages (from-to)309-313
JournalInorganic Chemistry Communications
Volume1
Issue number8
DOIs
Publication statusPublished - Aug 1998

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