TY - JOUR
T1 - Boron and Fluorine Co-doped Laser-Induced Graphene towards High-Performance Micro-Supercapacitors
AU - Yuan, Guanying
AU - Wan, Tong
AU - BaQais, Amal
AU - Mu, Yirui
AU - Cui, Dapeng
AU - Amin, Mohammed A.
AU - Li, Xiaodong
AU - Xu, Ben Bin
AU - Zhu, Xiaohan
AU - Algadi, Hassan
AU - Li, Handong
AU - Wasnik, Priyanka
AU - Lu, Na
AU - Guo, Zhanhu
AU - Wei, Huige
AU - Cheng, Bowen
N1 - Funding information: This work is financially supported by Young Elite Scientists Sponsorship Program by Tianjin (TJSQNTJ-2018-03). The authors acknowledge the financial support from Princess Nourah bint Abdulrahman University Researchers Supporting Project number (PNURSP2023R230), Princess Nourah bint Abdulrahman University, Riyadh, Saudi Arabia.
PY - 2023/8/1
Y1 - 2023/8/1
N2 - Laser-induced graphene (LIG) has attracted extensive research as an electrode material for micro-supercapacitors (MSC). However, the low capacitive performance of LIG arising from both limited specific surface area and few active sites remains challenging. Herein, in situ doping of fluorine and boron atoms into laser-induced graphene was innovatively achieved via laser direct writing approach using boron-doped fluorinated polyimide (FB-PI) as the precursor. The porous fluorine and boron co-doped laser-induced graphene (FB-LIG) exhibits more active sites and improved wettability and significantly enhanced capacitive performance due to the synergistic effect of fluorine and boron co-doping. By tuning the weight ratio of boron to fluorine, the MSC utilizing FB-LIG as the electrode and poly(vinyl alcohol) (PVA)/H2SO4 as the gel electrolyte delivers a high areal capacitance of 49.81 mF/cm2 at a current density of 0.09 mA/cm2, 23 times higher that of MSC from commercial polyimide (PI)-based LIG, and 3 times that of MSC from fluorinated PI-based LIG. In addition, MSCs from FB-LIG possess excellent mechanical stability and flexibility, rendering them promising for flexible wearable microelectronics.
AB - Laser-induced graphene (LIG) has attracted extensive research as an electrode material for micro-supercapacitors (MSC). However, the low capacitive performance of LIG arising from both limited specific surface area and few active sites remains challenging. Herein, in situ doping of fluorine and boron atoms into laser-induced graphene was innovatively achieved via laser direct writing approach using boron-doped fluorinated polyimide (FB-PI) as the precursor. The porous fluorine and boron co-doped laser-induced graphene (FB-LIG) exhibits more active sites and improved wettability and significantly enhanced capacitive performance due to the synergistic effect of fluorine and boron co-doping. By tuning the weight ratio of boron to fluorine, the MSC utilizing FB-LIG as the electrode and poly(vinyl alcohol) (PVA)/H2SO4 as the gel electrolyte delivers a high areal capacitance of 49.81 mF/cm2 at a current density of 0.09 mA/cm2, 23 times higher that of MSC from commercial polyimide (PI)-based LIG, and 3 times that of MSC from fluorinated PI-based LIG. In addition, MSCs from FB-LIG possess excellent mechanical stability and flexibility, rendering them promising for flexible wearable microelectronics.
KW - Boron doping
KW - Fluorinated polyimide
KW - Laser-induced graphene
KW - Micro-supercapacitors
UR - http://www.scopus.com/inward/record.url?scp=85160316782&partnerID=8YFLogxK
U2 - 10.1016/j.carbon.2023.118101
DO - 10.1016/j.carbon.2023.118101
M3 - Article
SN - 0008-6223
VL - 212
JO - Carbon
JF - Carbon
M1 - 118101
ER -