Chiral ligands: Unambiguous assignment of absolute configuration by NMR spectroscopy

Jonathan Bookham, William McFarlane

Research output: Contribution to journalArticlepeer-review

48 Citations (Scopus)

Abstract

Two-dimensional rotating-frame nuclear Overhauser enhancement (ROESY) spectra are used to determine the relative configurations at the chiral carbon atoms in the two diastereoisomers of [o-C6H4CHMeNMe 2Pd(Ph2PCHMeCHMePPh2)]+PF 6- derived from (+) Ph2PCHMeCHMePPh2 1 and [o-C6H4CHMeNMe2PdCl]2 of known configurations, and hence to show that the (+) form of 1 has the R,Rconfiguration.
Original languageEnglish
Pages (from-to)1352-1354
JournalJournal of the Chemical Society, Chemical Communications
Issue number17
DOIs
Publication statusPublished - 1993

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