Chiral ligands: Unambiguous assignment of absolute configuration by NMR spectroscopy

Jonathan Bookham; William McFarlane

doi:10.1039/C39930001352

Chiral ligands: Unambiguous assignment of absolute configuration by NMR spectroscopy

Jonathan Bookham, William McFarlane

Applied Sciences Department

Research output: Contribution to journal › Article › peer-review

49 Citations (Scopus)

Abstract

Two-dimensional rotating-frame nuclear Overhauser enhancement (ROESY) spectra are used to determine the relative configurations at the chiral carbon atoms in the two diastereoisomers of [o-C6H4CHMeNMe 2Pd(Ph2PCHMeCHMePPh2)]+PF 6- derived from (+) Ph2PCHMeCHMePPh2 1 and [o-C6H4CHMeNMe2PdCl]2 of known configurations, and hence to show that the (+) form of 1 has the R,Rconfiguration.

Original language	English
Pages (from-to)	1352-1354
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	17
DOIs	https://doi.org/10.1039/C39930001352
Publication status	Published - 1993

Access to Document

10.1039/C39930001352

Cite this

@article{1dea6a3bb8604d2690e51f7f415b29e2,

title = "Chiral ligands: Unambiguous assignment of absolute configuration by NMR spectroscopy",

abstract = "Two-dimensional rotating-frame nuclear Overhauser enhancement (ROESY) spectra are used to determine the relative configurations at the chiral carbon atoms in the two diastereoisomers of [o-C6H4CHMeNMe 2Pd(Ph2PCHMeCHMePPh2)]+PF 6- derived from (+) Ph2PCHMeCHMePPh2 1 and [o-C6H4CHMeNMe2PdCl]2 of known configurations, and hence to show that the (+) form of 1 has the R,Rconfiguration.",

author = "Jonathan Bookham and William McFarlane",

year = "1993",

doi = "10.1039/C39930001352",

language = "English",

pages = "1352--1354",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0577-6171",

publisher = "Royal Society of Chemistry",

number = "17",

}

TY - JOUR

T1 - Chiral ligands: Unambiguous assignment of absolute configuration by NMR spectroscopy

AU - Bookham, Jonathan

AU - McFarlane, William

PY - 1993

Y1 - 1993

N2 - Two-dimensional rotating-frame nuclear Overhauser enhancement (ROESY) spectra are used to determine the relative configurations at the chiral carbon atoms in the two diastereoisomers of [o-C6H4CHMeNMe 2Pd(Ph2PCHMeCHMePPh2)]+PF 6- derived from (+) Ph2PCHMeCHMePPh2 1 and [o-C6H4CHMeNMe2PdCl]2 of known configurations, and hence to show that the (+) form of 1 has the R,Rconfiguration.

AB - Two-dimensional rotating-frame nuclear Overhauser enhancement (ROESY) spectra are used to determine the relative configurations at the chiral carbon atoms in the two diastereoisomers of [o-C6H4CHMeNMe 2Pd(Ph2PCHMeCHMePPh2)]+PF 6- derived from (+) Ph2PCHMeCHMePPh2 1 and [o-C6H4CHMeNMe2PdCl]2 of known configurations, and hence to show that the (+) form of 1 has the R,Rconfiguration.

U2 - 10.1039/C39930001352

DO - 10.1039/C39930001352

M3 - Article

SN - 0577-6171

SP - 1352

EP - 1354

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 17

ER -

Chiral ligands: Unambiguous assignment of absolute configuration by NMR spectroscopy

Abstract

Access to Document

Fingerprint

Cite this