Abstract
Two-dimensional rotating-frame nuclear Overhauser enhancement (ROESY) spectra are used to determine the relative configurations at the chiral carbon atoms in the two diastereoisomers of [o-C6H4CHMeNMe 2Pd(Ph2PCHMeCHMePPh2)]+PF 6- derived from (+) Ph2PCHMeCHMePPh2 1 and [o-C6H4CHMeNMe2PdCl]2 of known configurations, and hence to show that the (+) form of 1 has the R,Rconfiguration.
| Original language | English |
|---|---|
| Pages (from-to) | 1352-1354 |
| Journal | Journal of the Chemical Society, Chemical Communications |
| Issue number | 17 |
| DOIs | |
| Publication status | Published - 1993 |
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