Conduction mechanisms in metal/self-assembled monolayer/metal junction

David Etor, Linzi E. Dodd, Claudio Balocco, David Wood

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    Abstract

    The conduction mechanisms in metal-insulator-metal (MIM) junctions where the insulator consists of a self-assembled monolayer are investigated. Temperature dependence measurements from 2.5 to 300 K, show that the conduction is dominated by tunnelling only for temperatures below 20 K, while at higher temperatures surface-limited and bulk-limited mechanisms are observed. The experimental results are explained using a combination of direct (Simmons) tunnelling, Schottky emission, and Poole-Frenkel theory. Further insight is gained through numerical simulations based on the non-equilibrium Green-function formalism.
    Original languageEnglish
    Pages (from-to)808-811
    JournalMicro and Nano Letters
    Volume14
    Issue number7
    Early online date7 Mar 2019
    DOIs
    Publication statusPublished - 26 Jun 2019

    Keywords

    • rectifier
    • electronic transport
    • self-assembly
    • current-conduction
    • temperature-dependence

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    • An Ultrathin Organic Insulator for Metal-Insulator-Metal Diodes

      Etor, D., Dodd, L. E., Wood, D. & Balocco, C., 20 Jun 2016, In: IEEE Transactions on Electron Devices. 63, 7, p. 2887-2891 5 p.

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      7 Citations (Scopus)
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    • Enhanced Narrow-Band Operation of Ultra-Fast Rectennas

      Etor, D., Dodd, L. E., Wood, D. & Balocco, C., 1 Dec 2016, 41st International Conference on Infrared, Millimeter and Terahertz Waves: IRMMW-THz 2016. IEEE, 2 p.

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      3 Citations (Scopus)
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    • High-performance rectifiers fabricated on a flexible substrate

      Etor, D., Dodd, L. E., Wood, D. & Balocco, C., 8 Nov 2016, In: Applied Physics Letters. 109, 19, 193110.

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      14 Citations (Scopus)
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