Conformationally Driven 2- and 3-Photon Cascade Processes in the Stereoselective Photorearrangement of Pyrroles

Paul Koovits, Jonathan Knowles, Kevin Booker-Milburn

Research output: Contribution to journalArticlepeer-review

9 Citations (Scopus)
4 Downloads (Pure)

Abstract

A TBSO group has been shown to exert a high degree of stereocontrol during the two-photon photocycloaddition/rearrangement of N-butenylpyrroles to complex tricyclic aziridines. Moreover, this and other bulky groups have been shown to change the outcome of the reaction, promoting a new two-photon sequence to tricyclic imines and an unprecedented stereoselective three-photon sequence to azabicyclo[3.3.1]nonanes.
Original languageEnglish
Pages (from-to)5608-5611
JournalOrganic Letters
Volume18
Issue number21
Early online date27 Oct 2016
DOIs
Publication statusPublished - 4 Nov 2016

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