Cu2ZnSnS4 thin films by simple replacement reaction route for solar photovoltaic application

Devendra Tiwari*, Tapas K. Chaudhuri, Arabinda Ray, Krishan Dutt Tiwari

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

23 Citations (Scopus)


A process for deposition of Cu2ZnSnS4 (CZTS) films using replacement of Zn2 + in ZnS is demonstrated. X-ray diffraction pattern and Raman spectroscopy confirm the formation of pure CZTS. Atomic force microscopy shows the films to be homogeneous and compact with root mean squared roughness of 6 nm. The direct band gap of CZTS films as elucidated by UV–Vis-NIR spectroscopy is 1.45 eV. The CZTS films exhibit p-type conduction with electrical conductivity of 4.6 S/cm. The hole concentration and hole mobility is determined to be 3.6 × 1017 cm− 3 and 1.4 cm2V− 1 s− 1 respectively. Solar cells with structure: graphite/CZTS/CdS/ZnO/SnO2:In/Soda lime glass are also fabricated, gave photo-conversion efficiency of 6.17% with open circuit voltage and short circuit current density of 521 mV and 19.13 mA/cm2, respectively and a high fill factor of 0.62. The external quantum efficiency of the solar cell lies above 60% in the visible region.
Original languageEnglish
Pages (from-to)42-45
Number of pages4
JournalThin Solid Films
Early online date1 Dec 2013
Publication statusPublished - 31 Jan 2014
Externally publishedYes


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