Ditopic bis-terdentate cyclometallating ligands and their highly luminescent dinuclear iridium(iii) complexes.

Pierre-Henri Lanoe; Chi Ming Tong; Ross Harrington; Michael Probert; William Clegg; J. A. Gareth Williams; Valery Kozhevnikov

doi:10.1039/C4CC01808G

Ditopic bis-terdentate cyclometallating ligands and their highly luminescent dinuclear iridium(iii) complexes.

Pierre-Henri Lanoe, Chi Ming Tong, Ross Harrington, Michael Probert, William Clegg, J. A. Gareth Williams, Valery Kozhevnikov

Applied Sciences Department

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Abstract

A new family of bridged cyclometallating ligands is reported, which incorporate two terdentate N(∧)C(∧)N-coordinating binding sites linked via pyrazine, pyrimidine or pyridazine units. Dinuclear Ir(iii) complexes of one ligand have been prepared and crystallographically characterised; they display intense red phosphorescence.

Original language	English
Pages (from-to)	6831-6834
Journal	Chemical Communications
Volume	50
DOIs	https://doi.org/10.1039/C4CC01808G
Publication status	Published - 4 Jul 2014

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title = "Ditopic bis-terdentate cyclometallating ligands and their highly luminescent dinuclear iridium(iii) complexes.",

abstract = "A new family of bridged cyclometallating ligands is reported, which incorporate two terdentate N(∧)C(∧)N-coordinating binding sites linked via pyrazine, pyrimidine or pyridazine units. Dinuclear Ir(iii) complexes of one ligand have been prepared and crystallographically characterised; they display intense red phosphorescence.",

author = "Pierre-Henri Lanoe and Tong, {Chi Ming} and Ross Harrington and Michael Probert and William Clegg and Williams, {J. A. Gareth} and Valery Kozhevnikov",

year = "2014",

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doi = "10.1039/C4CC01808G",

language = "English",

volume = "50",

pages = "6831--6834",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Ditopic bis-terdentate cyclometallating ligands and their highly luminescent dinuclear iridium(iii) complexes.

AU - Lanoe, Pierre-Henri

AU - Tong, Chi Ming

AU - Harrington, Ross

AU - Probert, Michael

AU - Clegg, William

AU - Williams, J. A. Gareth

AU - Kozhevnikov, Valery

PY - 2014/7/4

Y1 - 2014/7/4

N2 - A new family of bridged cyclometallating ligands is reported, which incorporate two terdentate N(∧)C(∧)N-coordinating binding sites linked via pyrazine, pyrimidine or pyridazine units. Dinuclear Ir(iii) complexes of one ligand have been prepared and crystallographically characterised; they display intense red phosphorescence.

AB - A new family of bridged cyclometallating ligands is reported, which incorporate two terdentate N(∧)C(∧)N-coordinating binding sites linked via pyrazine, pyrimidine or pyridazine units. Dinuclear Ir(iii) complexes of one ligand have been prepared and crystallographically characterised; they display intense red phosphorescence.

U2 - 10.1039/C4CC01808G

DO - 10.1039/C4CC01808G

M3 - Article

SN - 0022-4936

SN - 1359-7345

SN - 1364-548X

VL - 50

SP - 6831

EP - 6834

JO - Chemical Communications

JF - Chemical Communications

ER -

Ditopic bis-terdentate cyclometallating ligands and their highly luminescent dinuclear iridium(iii) complexes.

Abstract

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