Electrocatalytic Reduction of Carbon Dioxide with a Well-Defined PN3-Ru Pincer Complex

Shixiong Min; Shahid Rasul; Huaifeng Li; David C. Grills; Kazuhiro Takanabe; Lain Jong Li; Kuo Wei Huang

doi:10.1002/cplu.201500474

Electrocatalytic Reduction of Carbon Dioxide with a Well-Defined PN³-Ru Pincer Complex

Shixiong Min, Shahid Rasul, Huaifeng Li, David C. Grills, Kazuhiro Takanabe, Lain Jong Li, Kuo Wei Huang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

A well-defined PN³-Ru pincer complex (5) bearing a redox-active bipyridine ligand with an aminophosphine arm has been established as an effective and stable molecular electrocatalyst for CO₂ reduction to CO and HCOOH with negligible formation of H₂ in a H₂O/MeCN mixture. Done in a pince: A PN³-Ru pincer complex (see figure) has been found to show high activity and stability as a molecular electrocatalyst for CO₂ reduction to CO and HCOOH in MeCN/H₂O.

Original language	English
Pages (from-to)	166-171
Number of pages	6
Journal	ChemPlusChem
Volume	81
Issue number	2
Early online date	13 Nov 2015
DOIs	https://doi.org/10.1002/cplu.201500474
Publication status	Published - 1 Feb 2016

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 13 Climate Action

Keywords

electrocatalysts
electrochemistry
N,P ligands
redox
ruthenium

Access to Document

10.1002/cplu.201500474

Cite this

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title = "Electrocatalytic Reduction of Carbon Dioxide with a Well-Defined PN3-Ru Pincer Complex",

abstract = "A well-defined PN3-Ru pincer complex (5) bearing a redox-active bipyridine ligand with an aminophosphine arm has been established as an effective and stable molecular electrocatalyst for CO2 reduction to CO and HCOOH with negligible formation of H2 in a H2O/MeCN mixture. Done in a pince: A PN3-Ru pincer complex (see figure) has been found to show high activity and stability as a molecular electrocatalyst for CO2 reduction to CO and HCOOH in MeCN/H2O.",

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AU - Min, Shixiong

AU - Rasul, Shahid

AU - Li, Huaifeng

AU - Grills, David C.

AU - Takanabe, Kazuhiro

AU - Li, Lain Jong

AU - Huang, Kuo Wei

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AB - A well-defined PN3-Ru pincer complex (5) bearing a redox-active bipyridine ligand with an aminophosphine arm has been established as an effective and stable molecular electrocatalyst for CO2 reduction to CO and HCOOH with negligible formation of H2 in a H2O/MeCN mixture. Done in a pince: A PN3-Ru pincer complex (see figure) has been found to show high activity and stability as a molecular electrocatalyst for CO2 reduction to CO and HCOOH in MeCN/H2O.

KW - electrocatalysts

KW - electrochemistry

KW - N,P ligands

KW - redox

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