TY - JOUR
T1 - Enhanced electromagnetic wave absorption of magnetite-spinach derived carbon composite
AU - Yi, Yuan
AU - Zhao, Chunzhi
AU - Shindume, Hamukwaya l.
AU - Ren, Juanna
AU - Chen, Leilei
AU - Hou, Hua
AU - Ibrahim, Mohamed M.
AU - El-Bahy, Zeinhom M.
AU - Guo, Zhanhu
AU - Zhao, Zengying
AU - Gu, Junwei
PY - 2024/8/5
Y1 - 2024/8/5
N2 - The high density, high cost, and environmental pollution hinder the application of iron-based electromagnetic wave-absorbing materials. Although bio-carbon is a green and lightweight dielectric wave-absorbing material, the wave-absorbing performance of bio-carbon is still limited. This work successfully combined magnetite Fe3O4 with porous carbon derived from spinach stem using hydrothermal and calcination methods. This process optimizes the matching of the dielectric constant and magnetoconductivity of the as prepared composite material, resulting in a significant improvement in electromagnetic microwave absorption capacity. XRD, SEM, TEM, XPS, VSM and EMW absorption network analyzer are used to detect and characterize the samples. The composite material shows a excellent minimum reflection loss value of -48.81 dB and an efficacious absorption bandwidth of 4.73 GHz at the optimal raw material ratio. The tests also show the porous structure of the sample with the coercivity and saturation magnetization of 29.36 Oe and 10.75 emu/g, respectively. The test results indicate that the excellent electromagnetic wave absorption is due to the synergistic effect of multiple reflection, Debye relaxation, and interfacial polarization. This Fe3O4-bio-carbon composite is cheap and simple to prepare, and it also has excellent wave absorption performance. Therefore, it shows great application potential in civilian and military electromagnetic wave absorption fields.
AB - The high density, high cost, and environmental pollution hinder the application of iron-based electromagnetic wave-absorbing materials. Although bio-carbon is a green and lightweight dielectric wave-absorbing material, the wave-absorbing performance of bio-carbon is still limited. This work successfully combined magnetite Fe3O4 with porous carbon derived from spinach stem using hydrothermal and calcination methods. This process optimizes the matching of the dielectric constant and magnetoconductivity of the as prepared composite material, resulting in a significant improvement in electromagnetic microwave absorption capacity. XRD, SEM, TEM, XPS, VSM and EMW absorption network analyzer are used to detect and characterize the samples. The composite material shows a excellent minimum reflection loss value of -48.81 dB and an efficacious absorption bandwidth of 4.73 GHz at the optimal raw material ratio. The tests also show the porous structure of the sample with the coercivity and saturation magnetization of 29.36 Oe and 10.75 emu/g, respectively. The test results indicate that the excellent electromagnetic wave absorption is due to the synergistic effect of multiple reflection, Debye relaxation, and interfacial polarization. This Fe3O4-bio-carbon composite is cheap and simple to prepare, and it also has excellent wave absorption performance. Therefore, it shows great application potential in civilian and military electromagnetic wave absorption fields.
KW - Wave-absorbing material
KW - Bio-carbon
KW - Fe3O4
KW - Spinach
UR - http://www.scopus.com/inward/record.url?scp=85192796534&partnerID=8YFLogxK
U2 - 10.1016/j.colsurfa.2024.134149
DO - 10.1016/j.colsurfa.2024.134149
M3 - Article
SN - 0927-7757
VL - 694
JO - Colloids and Surfaces A: Physicochemical and Engineering Aspects
JF - Colloids and Surfaces A: Physicochemical and Engineering Aspects
M1 - 134149
ER -