Exploring the Zn-regulated function in Co–Zn catalysts for efficient hydrogenation of ethyl levulinate to γ-valerolactone

Jie Chu, Yafei Fan, Lu Sun, Changfu Zhuang, Yunxian Li, Xiaoqin Zou*, Chungang Min*, Xiaoteng Liu, Ying Wang*, Guangshan Zhu

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

8 Citations (Scopus)


A series of CoZn catalysts supported on N-doped porous carbon (Co xZn y@NPC-T) with controlled Zn content prepared at different calcination temperatures are studied for catalytic hydrogenation of biomass-based ethyl levulinate to γ-valerolactone, in which Zn is introduced as a regulator. The catalytic activity of optimum Co 3Zn 1@NPC-600 is 13 times higher than that of Co@NPC-600. The high activity of the catalyst is attributed to the Zn content: the amount of Zn not only regulates the content of active Co(0) and promotes the activation of hydrogen, but also affects the content of acidic sites and optimizes the adsorption of intermediates. Meanwhile, the content of Zn will also optimize the structural characteristics of the catalyst, thereby increasing the dispersion of active sites and mass transfer of the substrate. The regulated function of the Zn content, including electronic effects, acid site effects and size effects, is discussed in detail. In addition, the doping of Zn also helps to improve the stability of cycling performance. The strategy of adjusting the catalytic performance by the doping content provides support and examples for the rational design of highly active and stable catalysts.

Original languageEnglish
Pages (from-to)4325-4338
Number of pages14
JournalCatalysis Science and Technology
Issue number13
Early online date13 May 2022
Publication statusPublished - 7 Jul 2022


Dive into the research topics of 'Exploring the Zn-regulated function in Co–Zn catalysts for efficient hydrogenation of ethyl levulinate to γ-valerolactone'. Together they form a unique fingerprint.

Cite this