Facile synthesis of 6-aryl-3-pyridyl-1,2,4-triazines as a key step toward highly fluorescent 5-substituted bipyridines and their Zn(II) and Ru(II) complexes.

Valery Kozhevnikov; Olga Shabunina; Dmitry Kopchuk; Maria Ustinova; Burkhard Koenig; Dmitry Kozhevnikov

doi:10.1016/j.tet.2008.06.040

Facile synthesis of 6-aryl-3-pyridyl-1,2,4-triazines as a key step toward highly fluorescent 5-substituted bipyridines and their Zn(II) and Ru(II) complexes.

Valery Kozhevnikov, Olga Shabunina, Dmitry Kopchuk, Maria Ustinova, Burkhard Koenig, Dmitry Kozhevnikov

Applied Sciences Department

Research output: Contribution to journal › Article › peer-review

108 Citations (Scopus)

Abstract

A wide series of substituted bipyridines were obtained through the synthesis of 1,2,4-triazines and their aza Diels–Alder reactions. The reported method facilitates the synthesis of functionally diverse bipyridines that provides fine-tuning of photophysical properties of new ligands and their Zn(II) and Ru(II) complexes. Some of substituted bipyridines exhibit ‘off–on’ fluorescence response toward Zn2+ cations.

Original language	English
Journal	Tetrahedron
DOIs	https://doi.org/10.1016/j.tet.2008.06.040
Publication status	Published - Sept 2008

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10.1016/j.tet.2008.06.040

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title = "Facile synthesis of 6-aryl-3-pyridyl-1,2,4-triazines as a key step toward highly fluorescent 5-substituted bipyridines and their Zn(II) and Ru(II) complexes.",

abstract = "A wide series of substituted bipyridines were obtained through the synthesis of 1,2,4-triazines and their aza Diels–Alder reactions. The reported method facilitates the synthesis of functionally diverse bipyridines that provides fine-tuning of photophysical properties of new ligands and their Zn(II) and Ru(II) complexes. Some of substituted bipyridines exhibit {\textquoteleft}off–on{\textquoteright} fluorescence response toward Zn2+ cations.",

author = "Valery Kozhevnikov and Olga Shabunina and Dmitry Kopchuk and Maria Ustinova and Burkhard Koenig and Dmitry Kozhevnikov",

year = "2008",

month = sep,

doi = "10.1016/j.tet.2008.06.040",

language = "English",

journal = "Tetrahedron",

issn = "0040-4020",

publisher = "Elsevier",

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TY - JOUR

T1 - Facile synthesis of 6-aryl-3-pyridyl-1,2,4-triazines as a key step toward highly fluorescent 5-substituted bipyridines and their Zn(II) and Ru(II) complexes.

AU - Kozhevnikov, Valery

AU - Shabunina, Olga

AU - Kopchuk, Dmitry

AU - Ustinova, Maria

AU - Koenig, Burkhard

AU - Kozhevnikov, Dmitry

PY - 2008/9

Y1 - 2008/9

N2 - A wide series of substituted bipyridines were obtained through the synthesis of 1,2,4-triazines and their aza Diels–Alder reactions. The reported method facilitates the synthesis of functionally diverse bipyridines that provides fine-tuning of photophysical properties of new ligands and their Zn(II) and Ru(II) complexes. Some of substituted bipyridines exhibit ‘off–on’ fluorescence response toward Zn2+ cations.

AB - A wide series of substituted bipyridines were obtained through the synthesis of 1,2,4-triazines and their aza Diels–Alder reactions. The reported method facilitates the synthesis of functionally diverse bipyridines that provides fine-tuning of photophysical properties of new ligands and their Zn(II) and Ru(II) complexes. Some of substituted bipyridines exhibit ‘off–on’ fluorescence response toward Zn2+ cations.

U2 - 10.1016/j.tet.2008.06.040

DO - 10.1016/j.tet.2008.06.040

M3 - Article

SN - 0040-4020

JO - Tetrahedron

JF - Tetrahedron

ER -

Facile synthesis of 6-aryl-3-pyridyl-1,2,4-triazines as a key step toward highly fluorescent 5-substituted bipyridines and their Zn(II) and Ru(II) complexes.

Abstract

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