TY - JOUR
T1 - From 1,2,4-triazines towards substituted pyridines and their cyclometallated Pt complexes
AU - Kozhevnikov, Valery
AU - Ustinova, Maria
AU - Slepukhin, Pavel
AU - Santoro, Amedeo
AU - Bruce, Duncan
AU - Kozhevnikov, Dmitry
PY - 2008/6
Y1 - 2008/6
N2 - A new, efficient methodology for the synthesis of substituted thienylpyridines includes the synthesis of 3-thienyl-1,2,4-triazines using simple heterocyclisation followed by easy transformation of the triazine ring to a pyridine through an aza Diels–Alder approach. A variety of substituted pyridines can be easily achieved using cheap, commercially available reagents such as bromoacetylarenes, aroyl hydrazides, norbornadiene, and enamines in various combinations. New thienylpyridines form phosphorescent cyclometallated Pt complexes.
AB - A new, efficient methodology for the synthesis of substituted thienylpyridines includes the synthesis of 3-thienyl-1,2,4-triazines using simple heterocyclisation followed by easy transformation of the triazine ring to a pyridine through an aza Diels–Alder approach. A variety of substituted pyridines can be easily achieved using cheap, commercially available reagents such as bromoacetylarenes, aroyl hydrazides, norbornadiene, and enamines in various combinations. New thienylpyridines form phosphorescent cyclometallated Pt complexes.
UR - https://www.scopus.com/pages/publications/43849095790
U2 - 10.1016/j.tetlet.2008.04.138
DO - 10.1016/j.tetlet.2008.04.138
M3 - Article
SN - 0040-4039
VL - 49
SP - 4096
EP - 4098
JO - Tetrahedron Letters
JF - Tetrahedron Letters
IS - 26
ER -