Heck-Mizoroki Cross-Coupling of Vinyl Iodide and Applications in the Synthesis of Dienes and Trienes

Katrina Madden; Sylvain David; Jonathan Knowles; Andrew Whiting

doi:10.1039/c5cc03273c

Heck-Mizoroki Cross-Coupling of Vinyl Iodide and Applications in the Synthesis of Dienes and Trienes

Katrina Madden, Sylvain David, Jonathan Knowles, Andrew Whiting

Applied Sciences Department

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18 Citations (Scopus)

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Abstract

Vinyliodide reacts chemoselectively under Heck–Mizoroki conditions with terminal alkenes, including vinylboronate esters, to give dienes. The resulting dienylboronates undergo Suzuki–Miyaura couplings with aryl, heteroaryl and alkenyl halides to access dienes and trienes.

Original language	English
Pages (from-to)	11409-11412
Journal	Chemical Communications
Volume	51
Issue number	57
Early online date	11 Jun 2015
DOIs	https://doi.org/10.1039/c5cc03273c
Publication status	Published - 21 Jul 2015

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Chem Commun 2015 - author acceptedAccepted author manuscript, 592 KB

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title = "Heck-Mizoroki Cross-Coupling of Vinyl Iodide and Applications in the Synthesis of Dienes and Trienes",

abstract = "Vinyliodide reacts chemoselectively under Heck–Mizoroki conditions with terminal alkenes, including vinylboronate esters, to give dienes. The resulting dienylboronates undergo Suzuki–Miyaura couplings with aryl, heteroaryl and alkenyl halides to access dienes and trienes.",

author = "Katrina Madden and Sylvain David and Jonathan Knowles and Andrew Whiting",

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T1 - Heck-Mizoroki Cross-Coupling of Vinyl Iodide and Applications in the Synthesis of Dienes and Trienes

AU - Madden, Katrina

AU - David, Sylvain

AU - Knowles, Jonathan

AU - Whiting, Andrew

PY - 2015/7/21

Y1 - 2015/7/21

N2 - Vinyliodide reacts chemoselectively under Heck–Mizoroki conditions with terminal alkenes, including vinylboronate esters, to give dienes. The resulting dienylboronates undergo Suzuki–Miyaura couplings with aryl, heteroaryl and alkenyl halides to access dienes and trienes.

AB - Vinyliodide reacts chemoselectively under Heck–Mizoroki conditions with terminal alkenes, including vinylboronate esters, to give dienes. The resulting dienylboronates undergo Suzuki–Miyaura couplings with aryl, heteroaryl and alkenyl halides to access dienes and trienes.

U2 - 10.1039/c5cc03273c

DO - 10.1039/c5cc03273c

M3 - Article

SN - 1359-7345

VL - 51

SP - 11409

EP - 11412

JO - Chemical Communications

JF - Chemical Communications

IS - 57

ER -

Heck-Mizoroki Cross-Coupling of Vinyl Iodide and Applications in the Synthesis of Dienes and Trienes

Abstract

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