High-pressure phase equilibria for the binary system carbon dioxide + dibenzofuran

Eduardo Perez; Albertina Cabanas; Yolanda Sanchez-Vicente; Juan A. R. Renuncio; Concepcion Pando

doi:10.1016/j.supflu.2008.01.009

High-pressure phase equilibria for the binary system carbon dioxide + dibenzofuran

Eduardo Perez, Albertina Cabanas, Yolanda Sanchez-Vicente, Juan A. R. Renuncio, Concepcion Pando

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

The experimental solubility of dibenzofuran in near-critical and supercritical carbon dioxide and the solid–liquid–vapor (SLV) equilibrium line for the CO2 + dibenzofuran system are reported. The built in-house static view cell apparatus used in these measurements is described. The solubility of naphthalene in supercritical CO2 and the CO2 + naphthalene SLV line are also determined in order to assess the reliability and accuracy of the measurement technique. The solubility of dibenzofuran in carbon dioxide is determined at 301.3, 309.0, 319.2, 328.7 and 338.2 K in the 6–30 MPa pressure range. Solubility data are correlated using the Chrastil model and the Peng–Robinson equation of state. This equation is also used to predict the CO2 + dibenzofuran SLV line. Results show the feasibility of using supercritical CO2 to extract dibenzofuran.

Original language	English
Pages (from-to)	238-244
Number of pages	7
Journal	Journal of Supercritical Fluids
Volume	46
Issue number	3
Early online date	30 Jan 2008
DOIs	https://doi.org/10.1016/j.supflu.2008.01.009
Publication status	Published - Oct 2008
Externally published	Yes

Keywords

supercritical carbon dioxide
dibenzofuran
solubility
solid-liquid-vapor equilibrium
high-pressure phase equilibria

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10.1016/j.supflu.2008.01.009

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title = "High-pressure phase equilibria for the binary system carbon dioxide + dibenzofuran",

abstract = "The experimental solubility of dibenzofuran in near-critical and supercritical carbon dioxide and the solid–liquid–vapor (SLV) equilibrium line for the CO2 + dibenzofuran system are reported. The built in-house static view cell apparatus used in these measurements is described. The solubility of naphthalene in supercritical CO2 and the CO2 + naphthalene SLV line are also determined in order to assess the reliability and accuracy of the measurement technique. The solubility of dibenzofuran in carbon dioxide is determined at 301.3, 309.0, 319.2, 328.7 and 338.2 K in the 6–30 MPa pressure range. Solubility data are correlated using the Chrastil model and the Peng–Robinson equation of state. This equation is also used to predict the CO2 + dibenzofuran SLV line. Results show the feasibility of using supercritical CO2 to extract dibenzofuran.",

keywords = "supercritical carbon dioxide, dibenzofuran, solubility, solid-liquid-vapor equilibrium, high-pressure phase equilibria",

author = "Eduardo Perez and Albertina Cabanas and Yolanda Sanchez-Vicente and Renuncio, {Juan A. R.} and Concepcion Pando",

year = "2008",

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doi = "10.1016/j.supflu.2008.01.009",

language = "English",

volume = "46",

pages = "238--244",

journal = "Journal of Supercritical Fluids",

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TY - JOUR

T1 - High-pressure phase equilibria for the binary system carbon dioxide + dibenzofuran

AU - Perez, Eduardo

AU - Cabanas, Albertina

AU - Sanchez-Vicente, Yolanda

AU - Renuncio, Juan A. R.

AU - Pando, Concepcion

PY - 2008/10

Y1 - 2008/10

N2 - The experimental solubility of dibenzofuran in near-critical and supercritical carbon dioxide and the solid–liquid–vapor (SLV) equilibrium line for the CO2 + dibenzofuran system are reported. The built in-house static view cell apparatus used in these measurements is described. The solubility of naphthalene in supercritical CO2 and the CO2 + naphthalene SLV line are also determined in order to assess the reliability and accuracy of the measurement technique. The solubility of dibenzofuran in carbon dioxide is determined at 301.3, 309.0, 319.2, 328.7 and 338.2 K in the 6–30 MPa pressure range. Solubility data are correlated using the Chrastil model and the Peng–Robinson equation of state. This equation is also used to predict the CO2 + dibenzofuran SLV line. Results show the feasibility of using supercritical CO2 to extract dibenzofuran.

AB - The experimental solubility of dibenzofuran in near-critical and supercritical carbon dioxide and the solid–liquid–vapor (SLV) equilibrium line for the CO2 + dibenzofuran system are reported. The built in-house static view cell apparatus used in these measurements is described. The solubility of naphthalene in supercritical CO2 and the CO2 + naphthalene SLV line are also determined in order to assess the reliability and accuracy of the measurement technique. The solubility of dibenzofuran in carbon dioxide is determined at 301.3, 309.0, 319.2, 328.7 and 338.2 K in the 6–30 MPa pressure range. Solubility data are correlated using the Chrastil model and the Peng–Robinson equation of state. This equation is also used to predict the CO2 + dibenzofuran SLV line. Results show the feasibility of using supercritical CO2 to extract dibenzofuran.

KW - supercritical carbon dioxide

KW - dibenzofuran

KW - solubility

KW - solid-liquid-vapor equilibrium

KW - high-pressure phase equilibria

U2 - 10.1016/j.supflu.2008.01.009

DO - 10.1016/j.supflu.2008.01.009

M3 - Article

SN - 0896-8446

VL - 46

SP - 238

EP - 244

JO - Journal of Supercritical Fluids

JF - Journal of Supercritical Fluids

IS - 3

ER -

High-pressure phase equilibria for the binary system carbon dioxide + dibenzofuran

Abstract

Keywords

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