TY - JOUR
T1 - Influence of Different Substrates on the Properties of Sulfurized SnS Films
AU - Reddy, Vasudeva Reddy Minnam
AU - Gedi, Sreedevi
AU - Pejjai, Babu
AU - Ramakrishna Reddy, Kotte
AU - Zoppi, Guillaume
AU - Park, Chinho
PY - 2016/1/1
Y1 - 2016/1/1
N2 - SnS films were grown on a variety of substrates, such as Al, Si, Mo, Ni, ITO, and glass, maintaining a constant sulfurization temperature of 350 C and time of 150 min using elemental sulfur via a two-stage process. The influence of the various types of substrates on the growth and physical properties was examined by Xray diffraction (XRD), Raman spectroscopy, scanning electron microscopy, and electrical measurements. The XRD profiles indicated that the as-prepared films were in a polycrystalline nature with different planes as the preferred orientations and exhibited an orthorhombic crystal structure. The Raman spectra revealed bands at 95 cm−1, 189 cm−1 and 219 cm−1; and 163 cm−1, which were assigned to the Ag and B2g phonon modes of SnS, respectively. The surface morphology revealed complete coverage of the grains with good compactness. Electrical studies yielded interesting results in that the SnS films grown on glass substrates showed a higher electrical resistivity of 45 -cm compared to the other substrates but all the films exhibited p-type conductivity.
AB - SnS films were grown on a variety of substrates, such as Al, Si, Mo, Ni, ITO, and glass, maintaining a constant sulfurization temperature of 350 C and time of 150 min using elemental sulfur via a two-stage process. The influence of the various types of substrates on the growth and physical properties was examined by Xray diffraction (XRD), Raman spectroscopy, scanning electron microscopy, and electrical measurements. The XRD profiles indicated that the as-prepared films were in a polycrystalline nature with different planes as the preferred orientations and exhibited an orthorhombic crystal structure. The Raman spectra revealed bands at 95 cm−1, 189 cm−1 and 219 cm−1; and 163 cm−1, which were assigned to the Ag and B2g phonon modes of SnS, respectively. The surface morphology revealed complete coverage of the grains with good compactness. Electrical studies yielded interesting results in that the SnS films grown on glass substrates showed a higher electrical resistivity of 45 -cm compared to the other substrates but all the films exhibited p-type conductivity.
KW - Different substrates
KW - electrical properties
KW - structural analysis
KW - sulfurization
U2 - 10.1166/sam.2016.2638
DO - 10.1166/sam.2016.2638
M3 - Article
SN - 1947-2935
VL - 8
SP - 247
EP - 251
JO - Science of Advanced Materials
JF - Science of Advanced Materials
IS - 1
ER -