Low cost materials for fluoride removal from groundwater

In several parts of the world, high fluoride concentrations in groundwater have been reported.Fluoride concentrations above the World Health Organization's (WHO) threshold level of 1.5 mg/L in drinkable water pose a health concern for communities and the environment. The distribution of fluoride is mainly related to the geological environment: rocks that contain fluorine, for example basalt, shale, and granite, release their respective minerals containing fluoride to the groundwater by dissolution. Excessive fluoride intake leads to dental and skeletal fluorosis, fragile bones, cancer, infertility, damage to the brain function, Alzheimer syndrome, and thyroid disorder. Cheap, abundant, and locally available fluoride removal techniques are needed to meet the requirement for fluoride-free drinking water in developing countries, especially in rural communities. Different conventional methods, such as membrane technologies, ion exchange, coagulation and precipitation techniques, are employed to remove fluoride from drinking water. However, only a few of these techniques can be applied at large-scale in developing countries due to their high investment costs, high maintenance and operating costs, and the possibility of producing toxic intermediates during the treatment process. Unlike conventional methods, adsorption is a promising technology due to its simple operation in a batch or continuous systems, simple design, low-cost of operation and wide range of locally available adsorbents. Adsorption is widely applied for removing fluoride from groundwater and wastewater, effectively maintaining water quality and taste. Based on the review, adsorption stands out as the best method for fluoride removal, considering surface modification and regeneration to increase the efficiency of adsorbent materials. This makes it an ideal solution for ensuring safe drinking water in resource-limited settings.