Magnetic field facilitated electrocatalytic degradation of tetracycline in wastewater by magnetic porous carbonized phthalonitrile resin

Junling  Zeng; Wenhao  Xie; Ying Guo; Tong  Zhao; Heng  Zhou; Qiaoying  Wang; Handong Li; Zhanhu Guo; Ben Bin Xu; Hongbo  Gu

doi:10.1016/j.apcatb.2023.123225

Magnetic field facilitated electrocatalytic degradation of tetracycline in wastewater by magnetic porous carbonized phthalonitrile resin

Junling Zeng, Wenhao Xie, Ying Guo, Tong Zhao, Heng Zhou^*, Qiaoying Wang, Handong Li, Zhanhu Guo, Ben Bin Xu, Hongbo Gu^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

65 Citations (Scopus)

Abstract

Herein, the magnetic field facilitated electrocatalytic degradation of tetracycline is reported for the first time. A magnetic porous carbonized phthalonitrile resin electrocatalyst has been prepared through directly annealing phthalonitrile monomer, polyaniline coated barium ferrite and potassium hydroxide. The tetracycline degradation percentage (DP%) by such electrocatalyst is significantly increased up to 37.42% under magnetic field with the optimal pH value of 5.0 and bias voltage of 1.0 V (vs. SCE). The mechanism of this phenomenon is explained by the spin-selective electron removal process in the reaction between metal-oxygen species and tetracycline on the electrocatalyst. The comparison of degradation pathways for tetracycline with and without magnetic field confirms the improvement of tetracycline DP%. This work opens a new direction for the application of an external magnetic field in the electrocatalytic degradation of antibiotics in wastewater.

Original language	English
Article number	123225
Number of pages	10
Journal	Applied Catalysis B: Environmental
Volume	340
Early online date	25 Aug 2023
DOIs	https://doi.org/10.1016/j.apcatb.2023.123225
Publication status	Published - 1 Jan 2024

Keywords

Tetracycline
Electrocatalytic degradation
Carbonized phthalonitrile resin
Magnetic field effect
Spin polarization

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10.1016/j.apcatb.2023.123225

Magnetic_filed_TC_DE_17_revisedAccepted author manuscript, 1.26 MBLicence: CC BY-NC-ND

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title = "Magnetic field facilitated electrocatalytic degradation of tetracycline in wastewater by magnetic porous carbonized phthalonitrile resin",

abstract = "Herein, the magnetic field facilitated electrocatalytic degradation of tetracycline is reported for the first time. A magnetic porous carbonized phthalonitrile resin electrocatalyst has been prepared through directly annealing phthalonitrile monomer, polyaniline coated barium ferrite and potassium hydroxide. The tetracycline degradation percentage (DP%) by such electrocatalyst is significantly increased up to 37.42% under magnetic field with the optimal pH value of 5.0 and bias voltage of 1.0 V (vs. SCE). The mechanism of this phenomenon is explained by the spin-selective electron removal process in the reaction between metal-oxygen species and tetracycline on the electrocatalyst. The comparison of degradation pathways for tetracycline with and without magnetic field confirms the improvement of tetracycline DP%. This work opens a new direction for the application of an external magnetic field in the electrocatalytic degradation of antibiotics in wastewater.",

keywords = "Tetracycline, Electrocatalytic degradation, Carbonized phthalonitrile resin, Magnetic field effect, Spin polarization",

author = "Junling Zeng and Wenhao Xie and Ying Guo and Tong Zhao and Heng Zhou and Qiaoying Wang and Handong Li and Zhanhu Guo and Xu, {Ben Bin} and Hongbo Gu",

note = "Funding information: The authors are grateful for the support from Fundamental Research Funds for the Central Universities and the Foundation of National Natural Science Foundation of China (No. 52003272). This work is supported by Shanghai Science and Technology Commission (19DZ2271500).",

year = "2024",

month = jan,

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doi = "10.1016/j.apcatb.2023.123225",

language = "English",

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TY - JOUR

T1 - Magnetic field facilitated electrocatalytic degradation of tetracycline in wastewater by magnetic porous carbonized phthalonitrile resin

AU - Zeng, Junling

AU - Xie, Wenhao

AU - Guo, Ying

AU - Zhao, Tong

AU - Zhou, Heng

AU - Wang, Qiaoying

AU - Li, Handong

AU - Guo, Zhanhu

AU - Xu, Ben Bin

AU - Gu, Hongbo

N1 - Funding information: The authors are grateful for the support from Fundamental Research Funds for the Central Universities and the Foundation of National Natural Science Foundation of China (No. 52003272). This work is supported by Shanghai Science and Technology Commission (19DZ2271500).

PY - 2024/1/1

Y1 - 2024/1/1

N2 - Herein, the magnetic field facilitated electrocatalytic degradation of tetracycline is reported for the first time. A magnetic porous carbonized phthalonitrile resin electrocatalyst has been prepared through directly annealing phthalonitrile monomer, polyaniline coated barium ferrite and potassium hydroxide. The tetracycline degradation percentage (DP%) by such electrocatalyst is significantly increased up to 37.42% under magnetic field with the optimal pH value of 5.0 and bias voltage of 1.0 V (vs. SCE). The mechanism of this phenomenon is explained by the spin-selective electron removal process in the reaction between metal-oxygen species and tetracycline on the electrocatalyst. The comparison of degradation pathways for tetracycline with and without magnetic field confirms the improvement of tetracycline DP%. This work opens a new direction for the application of an external magnetic field in the electrocatalytic degradation of antibiotics in wastewater.

AB - Herein, the magnetic field facilitated electrocatalytic degradation of tetracycline is reported for the first time. A magnetic porous carbonized phthalonitrile resin electrocatalyst has been prepared through directly annealing phthalonitrile monomer, polyaniline coated barium ferrite and potassium hydroxide. The tetracycline degradation percentage (DP%) by such electrocatalyst is significantly increased up to 37.42% under magnetic field with the optimal pH value of 5.0 and bias voltage of 1.0 V (vs. SCE). The mechanism of this phenomenon is explained by the spin-selective electron removal process in the reaction between metal-oxygen species and tetracycline on the electrocatalyst. The comparison of degradation pathways for tetracycline with and without magnetic field confirms the improvement of tetracycline DP%. This work opens a new direction for the application of an external magnetic field in the electrocatalytic degradation of antibiotics in wastewater.

KW - Tetracycline

KW - Electrocatalytic degradation

KW - Carbonized phthalonitrile resin

KW - Magnetic field effect

KW - Spin polarization

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U2 - 10.1016/j.apcatb.2023.123225

DO - 10.1016/j.apcatb.2023.123225

M3 - Article

SN - 0926-3373

VL - 340

JO - Applied Catalysis B: Environmental

JF - Applied Catalysis B: Environmental

M1 - 123225

ER -

Magnetic field facilitated electrocatalytic degradation of tetracycline in wastewater by magnetic porous carbonized phthalonitrile resin

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Keywords

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