Multi-analytical examination of the surface layers of the V&A cast of the tombstone of the Presbyter Bruno

Valentina Risdonne, Charlotte Hubbard, Johanna Puisto, Charis Theodorakopoulos*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

A multi-analytical study was designed to characterise historical coated plaster surfaces.The method was applied to investigate the surface coatings of the nineteenth-century plaster cast of the tombstone of the Presbyter Bruno that belongs to the Victoria and Albert Museum collection. At first, selected samples of the object were examined with Visible Light Reflectance and Ultra-Violet Fluorescence Optical Microscopy (VLR- andUVf-OM respectively) and Scanning Electron Microscopy (SEM) demonstrating a consistent stratigraphy featuring a bulk, an interface and an uppermost layer. The latter layer appeared to consist of an aged coating and dirt. Over painted and repaired areas of the object generated samples that had additional layers on top of the aforementioned stratigraphy. A layer that seemed to be an additional surface varnish or a coating that had not been absorbed to the bulk has been observed in a couple of samples. Elemental characterization was carried out with energy dispersive x-rayspectroscopy (EDS) and further analyses were performed with x-ray diffraction (XRD)and Fourier-transform infrared (FT-IR) spectroscopy with focal plane array (FPA) imaging which confirmed that the bulk of the object is made of gypsum plaster containing mostly silicate and carbonate inclusions. Gas Chromatography/mass spectrometry (GC/MS) and pyrolysis-GC/MS with extraction methods based on npropanol followed by pentafluoropropionic anhydride (PFPA), tetramethylammonium hydroxide (TMAH) and 3-trifluoromethylphenyltrimethylammonium hydroxide (m-TFPTAH) were performed to detect organic media. The results suggest that the organic medium used for the surface coating is a diterpenic resin that contained silicon,aluminium and traces of other inorganic elements. The organic medium of overpainted areas was based on alkyd resins and the in-paints were characterised as a blend of silicon and barium at varied concentrations. This multi-analytical approach can generate a better understanding of manufacturing, component materials and conservation issues of coated plaster objects.
Original languageEnglish
JournalHeritage Science
Publication statusAccepted/In press - 11 May 2021

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