Nickel catalyzed one pot synthesis of biaryls under air at room temperature

Aparna Bhat; Fawad Inam; Badekai Ramachandra Bhat

doi:10.1039/C3RA43363C

Nickel catalyzed one pot synthesis of biaryls under air at room temperature

Aparna Bhat, Fawad Inam, Badekai Ramachandra Bhat

Mechanical and Construction Engineering Department

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8 Citations (Scopus)

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Abstract

A practical, room temperature catalytic system has been developed for the synthesis of biaryls in one step from the homocoupling of in situ generated Grignard reagents using the nickel(II) complex. Molecular oxygen used as an oxidant makes the system environment friendly. The reaction system is compatible with diverse functionality to afford biaryls in appreciable yields.

Original language	English
Pages (from-to)	22191-22198
Journal	RSC Advances
Volume	44
Issue number	3
DOIs	https://doi.org/10.1039/C3RA43363C
Publication status	Published - 6 Sept 2013

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title = "Nickel catalyzed one pot synthesis of biaryls under air at room temperature",

abstract = "A practical, room temperature catalytic system has been developed for the synthesis of biaryls in one step from the homocoupling of in situ generated Grignard reagents using the nickel(II) complex. Molecular oxygen used as an oxidant makes the system environment friendly. The reaction system is compatible with diverse functionality to afford biaryls in appreciable yields.",

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AU - Inam, Fawad

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Y1 - 2013/9/6

N2 - A practical, room temperature catalytic system has been developed for the synthesis of biaryls in one step from the homocoupling of in situ generated Grignard reagents using the nickel(II) complex. Molecular oxygen used as an oxidant makes the system environment friendly. The reaction system is compatible with diverse functionality to afford biaryls in appreciable yields.

AB - A practical, room temperature catalytic system has been developed for the synthesis of biaryls in one step from the homocoupling of in situ generated Grignard reagents using the nickel(II) complex. Molecular oxygen used as an oxidant makes the system environment friendly. The reaction system is compatible with diverse functionality to afford biaryls in appreciable yields.

U2 - 10.1039/C3RA43363C

DO - 10.1039/C3RA43363C

M3 - Article

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VL - 44

SP - 22191

EP - 22198

JO - RSC Advances

JF - RSC Advances

IS - 3

ER -

Nickel catalyzed one pot synthesis of biaryls under air at room temperature

Abstract

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