Nickel hydroxide/ cobalt–ferrite magnetic nanocatalyst for alcohol oxidation

Pooja Bhat; Fawad Inam; Badekai Ramachandra Bhat

doi:10.1021/co500031b

Nickel hydroxide/ cobalt–ferrite magnetic nanocatalyst for alcohol oxidation

Pooja Bhat, Fawad Inam, Badekai Ramachandra Bhat

Mechanical and Construction Engineering

Research output: Contribution to journal › Article › peer-review

36 Citations (Scopus)

Abstract

A magnetically separable, active nickel hydroxide (Brønsted base) coated nanocobalt ferrite catalyst has been developed for oxidation of alcohols. High surface area was achieved by tuning the particle size with surfactant. The surface area of 120.94 m2 g–1 has been achieved for the coated nanocobalt ferrite. Improved catalytic activity and selectivity were obtained by synergistic effect of transition metal hydroxide (basic hydroxide) on nanocobalt ferrite. The nanocatalyst oxidizes primary and secondary alcohols efficiently (87%) to corresponding carbonyls in good yields.

Original language	English
Pages (from-to)	397-402
Journal	ACS Combinatorial Science
Volume	16
Issue number	8
DOIs	https://doi.org/10.1021/co500031b
Publication status	Published - Aug 2014

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10.1021/co500031b

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title = "Nickel hydroxide/ cobalt–ferrite magnetic nanocatalyst for alcohol oxidation",

abstract = "A magnetically separable, active nickel hydroxide (Br{\o}nsted base) coated nanocobalt ferrite catalyst has been developed for oxidation of alcohols. High surface area was achieved by tuning the particle size with surfactant. The surface area of 120.94 m2 g–1 has been achieved for the coated nanocobalt ferrite. Improved catalytic activity and selectivity were obtained by synergistic effect of transition metal hydroxide (basic hydroxide) on nanocobalt ferrite. The nanocatalyst oxidizes primary and secondary alcohols efficiently (87%) to corresponding carbonyls in good yields.",

keywords = "nano cobalt ferrite, transition metal hydroxide, high surface area, alcohol oxidation",

author = "Pooja Bhat and Fawad Inam and Bhat, {Badekai Ramachandra}",

note = "Published online first.",

year = "2014",

month = aug,

doi = "10.1021/co500031b",

language = "English",

volume = "16",

pages = "397--402",

journal = "ACS Combinatorial Science",

issn = "2156-8952",

publisher = "American Chemical Society",

number = "8",

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TY - JOUR

T1 - Nickel hydroxide/ cobalt–ferrite magnetic nanocatalyst for alcohol oxidation

AU - Bhat, Pooja

AU - Inam, Fawad

AU - Bhat, Badekai Ramachandra

N1 - Published online first.

PY - 2014/8

Y1 - 2014/8

N2 - A magnetically separable, active nickel hydroxide (Brønsted base) coated nanocobalt ferrite catalyst has been developed for oxidation of alcohols. High surface area was achieved by tuning the particle size with surfactant. The surface area of 120.94 m2 g–1 has been achieved for the coated nanocobalt ferrite. Improved catalytic activity and selectivity were obtained by synergistic effect of transition metal hydroxide (basic hydroxide) on nanocobalt ferrite. The nanocatalyst oxidizes primary and secondary alcohols efficiently (87%) to corresponding carbonyls in good yields.

AB - A magnetically separable, active nickel hydroxide (Brønsted base) coated nanocobalt ferrite catalyst has been developed for oxidation of alcohols. High surface area was achieved by tuning the particle size with surfactant. The surface area of 120.94 m2 g–1 has been achieved for the coated nanocobalt ferrite. Improved catalytic activity and selectivity were obtained by synergistic effect of transition metal hydroxide (basic hydroxide) on nanocobalt ferrite. The nanocatalyst oxidizes primary and secondary alcohols efficiently (87%) to corresponding carbonyls in good yields.

KW - nano cobalt ferrite

KW - transition metal hydroxide

KW - high surface area

KW - alcohol oxidation

UR - http://pubs.acs.org/doi/abs/10.1021/co500031b

U2 - 10.1021/co500031b

DO - 10.1021/co500031b

M3 - Article

SN - 2156-8952

VL - 16

SP - 397

EP - 402

JO - ACS Combinatorial Science

JF - ACS Combinatorial Science

IS - 8

ER -

Nickel hydroxide/ cobalt–ferrite magnetic nanocatalyst for alcohol oxidation

Abstract

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