TY - JOUR
T1 - Novel rate equations describing isochronous chemical reactions
AU - Calogero, Francesco
AU - Leyvraz, François
AU - Sommacal, Matteo
PY - 2011
Y1 - 2011
N2 - A simple mathematical model involving two first-order Ordinary Differential Equations (ODEs) with fourth-degree polynomial nonlinearities is introduced. The initial-value problem for this system of two ODEs is solved in terms of elementary functions: for an open set of initial data, this solution is isochronous, i.e., completely periodic with a fixed period (independent of the initial data); in the complementary set of initial data, it blows up at a finite time. This system is likely to be of applicative interest: for instance it models the time evolution of two chemical substances in a spatially homogeneous situation, provided this evolution is characterized by six appropriate chemical reactions whose rates are simply expressed in terms of three a priori arbitrary parameters, or alternatively by five appropriate reactions whose rates are simply expressed in terms of two a priori arbitrary parameters.
AB - A simple mathematical model involving two first-order Ordinary Differential Equations (ODEs) with fourth-degree polynomial nonlinearities is introduced. The initial-value problem for this system of two ODEs is solved in terms of elementary functions: for an open set of initial data, this solution is isochronous, i.e., completely periodic with a fixed period (independent of the initial data); in the complementary set of initial data, it blows up at a finite time. This system is likely to be of applicative interest: for instance it models the time evolution of two chemical substances in a spatially homogeneous situation, provided this evolution is characterized by six appropriate chemical reactions whose rates are simply expressed in terms of three a priori arbitrary parameters, or alternatively by five appropriate reactions whose rates are simply expressed in terms of two a priori arbitrary parameters.
KW - oscillatory chemical reactions
KW - rate equations
KW - isochronous systems
U2 - 10.1007/s10910-010-9784-1
DO - 10.1007/s10910-010-9784-1
M3 - Article
VL - 49
SP - 870
EP - 879
JO - Journal of Mathematical Chemistry
JF - Journal of Mathematical Chemistry
SN - 0259-9791
IS - 4
ER -