Nucleophilic Substitution of Fluorine Atoms in 2,6-Difluoro-3-(pyridin-2-yl)benzonitrile Leading to Soluble Blue-Emitting Cyclometalated Ir(III) Complexes

Valery Kozhevnikov; Katja Dahms; Martin Bryce

doi:10.1021/jo200357e

Nucleophilic Substitution of Fluorine Atoms in 2,6-Difluoro-3-(pyridin-2-yl)benzonitrile Leading to Soluble Blue-Emitting Cyclometalated Ir(III) Complexes

Valery Kozhevnikov, Katja Dahms, Martin Bryce

Applied Sciences Department

Research output: Contribution to journal › Article › peer-review

36 Citations (Scopus)

Abstract

New functionalized phenylpyridine ligands and their derived heteroleptic cyclometalated Ir(III) complexes have been synthesized. The complexes possess a combination of important properties: (i) blue emission, (ii) good photoluminescence quantum yields, and (iii) good solubility in organic solvents, making them very attractive as phosphorescent dopant emitters for solution-processable light-emitting devices.

Original language	English
Pages (from-to)	5143-5148
Journal	The Journal of Organic Chemistry
Volume	76
Issue number	12
DOIs	https://doi.org/10.1021/jo200357e
Publication status	Published - 2011

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10.1021/jo200357e

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title = "Nucleophilic Substitution of Fluorine Atoms in 2,6-Difluoro-3-(pyridin-2-yl)benzonitrile Leading to Soluble Blue-Emitting Cyclometalated Ir(III) Complexes",

abstract = "New functionalized phenylpyridine ligands and their derived heteroleptic cyclometalated Ir(III) complexes have been synthesized. The complexes possess a combination of important properties: (i) blue emission, (ii) good photoluminescence quantum yields, and (iii) good solubility in organic solvents, making them very attractive as phosphorescent dopant emitters for solution-processable light-emitting devices.",

author = "Valery Kozhevnikov and Katja Dahms and Martin Bryce",

year = "2011",

doi = "10.1021/jo200357e",

language = "English",

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journal = "The Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

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T1 - Nucleophilic Substitution of Fluorine Atoms in 2,6-Difluoro-3-(pyridin-2-yl)benzonitrile Leading to Soluble Blue-Emitting Cyclometalated Ir(III) Complexes

AU - Kozhevnikov, Valery

AU - Dahms, Katja

AU - Bryce, Martin

PY - 2011

Y1 - 2011

N2 - New functionalized phenylpyridine ligands and their derived heteroleptic cyclometalated Ir(III) complexes have been synthesized. The complexes possess a combination of important properties: (i) blue emission, (ii) good photoluminescence quantum yields, and (iii) good solubility in organic solvents, making them very attractive as phosphorescent dopant emitters for solution-processable light-emitting devices.

AB - New functionalized phenylpyridine ligands and their derived heteroleptic cyclometalated Ir(III) complexes have been synthesized. The complexes possess a combination of important properties: (i) blue emission, (ii) good photoluminescence quantum yields, and (iii) good solubility in organic solvents, making them very attractive as phosphorescent dopant emitters for solution-processable light-emitting devices.

U2 - 10.1021/jo200357e

DO - 10.1021/jo200357e

M3 - Article

SN - 0022-3263

SN - 1520-6904

VL - 76

SP - 5143

EP - 5148

JO - The Journal of Organic Chemistry

JF - The Journal of Organic Chemistry

IS - 12

ER -

Nucleophilic Substitution of Fluorine Atoms in 2,6-Difluoro-3-(pyridin-2-yl)benzonitrile Leading to Soluble Blue-Emitting Cyclometalated Ir(III) Complexes

Abstract

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