Nucleophilic substitution of hydrogen in the reaction of 1,2,4-triazin-4-oxides with cyanamide

V. N. Kozhevnikov; A. M. Prokhorov; D. N. Kozhevnikov; V. L. Rusinov; O. N. Chupakhin

doi:10.1007/BF02494908

Nucleophilic substitution of hydrogen in the reaction of 1,2,4-triazin-4-oxides with cyanamide

V. N. Kozhevnikov, A. M. Prokhorov, D. N. Kozhevnikov, V. L. Rusinov, O. N. Chupakhin

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

It was shown that cyanamide can successfully be used in reactions of nucleophilic substitution of hydrogen with 1,2,4-triazin-4-oxides in the presence of a base to give 5-cyanoimino-1,2,4-triazines. It was found by ¹³C NMR spectroscopy that these compounds and their alkylalion products at the cyclic nitrogen atom exist in the form of 5-cyanoimino-2,5-dihydro-1,2,4-triazines.

Original language	English
Pages (from-to)	1122-1124
Number of pages	3
Journal	Russian Chemical Bulletin
Volume	49
Issue number	6
DOIs	https://doi.org/10.1007/BF02494908
Publication status	Published - Jun 2000
Externally published	Yes

Keywords

1,2,4-triazin-4-oxides
5-cyanoimino-1,2,4-triazines
H and C NMR spectroscopy
Cyanamide
Nucleophilic substitution of hydrogen

Access to Document

10.1007/BF02494908

Cite this

@article{6e02fc630c0f474fad1a35a14098569f,

title = "Nucleophilic substitution of hydrogen in the reaction of 1,2,4-triazin-4-oxides with cyanamide",

abstract = "It was shown that cyanamide can successfully be used in reactions of nucleophilic substitution of hydrogen with 1,2,4-triazin-4-oxides in the presence of a base to give 5-cyanoimino-1,2,4-triazines. It was found by 13C NMR spectroscopy that these compounds and their alkylalion products at the cyclic nitrogen atom exist in the form of 5-cyanoimino-2,5-dihydro-1,2,4-triazines.",

keywords = "1,2,4-triazin-4-oxides, 5-cyanoimino-1,2,4-triazines, H and C NMR spectroscopy, Cyanamide, Nucleophilic substitution of hydrogen",

author = "Kozhevnikov, \{V. N.\} and Prokhorov, \{A. M.\} and Kozhevnikov, \{D. N.\} and Rusinov, \{V. L.\} and Chupakhin, \{O. N.\}",

year = "2000",

month = jun,

doi = "10.1007/BF02494908",

language = "English",

volume = "49",

pages = "1122--1124",

journal = "Russian Chemical Bulletin",

issn = "1066-5285",

publisher = "Springer",

number = "6",

}

TY - JOUR

T1 - Nucleophilic substitution of hydrogen in the reaction of 1,2,4-triazin-4-oxides with cyanamide

AU - Kozhevnikov, V. N.

AU - Prokhorov, A. M.

AU - Kozhevnikov, D. N.

AU - Rusinov, V. L.

AU - Chupakhin, O. N.

PY - 2000/6

Y1 - 2000/6

N2 - It was shown that cyanamide can successfully be used in reactions of nucleophilic substitution of hydrogen with 1,2,4-triazin-4-oxides in the presence of a base to give 5-cyanoimino-1,2,4-triazines. It was found by 13C NMR spectroscopy that these compounds and their alkylalion products at the cyclic nitrogen atom exist in the form of 5-cyanoimino-2,5-dihydro-1,2,4-triazines.

AB - It was shown that cyanamide can successfully be used in reactions of nucleophilic substitution of hydrogen with 1,2,4-triazin-4-oxides in the presence of a base to give 5-cyanoimino-1,2,4-triazines. It was found by 13C NMR spectroscopy that these compounds and their alkylalion products at the cyclic nitrogen atom exist in the form of 5-cyanoimino-2,5-dihydro-1,2,4-triazines.

KW - 1,2,4-triazin-4-oxides

KW - 5-cyanoimino-1,2,4-triazines

KW - H and C NMR spectroscopy

KW - Cyanamide

KW - Nucleophilic substitution of hydrogen

UR - https://www.scopus.com/pages/publications/0034339417

U2 - 10.1007/BF02494908

DO - 10.1007/BF02494908

M3 - Article

AN - SCOPUS:0034339417

SN - 1066-5285

VL - 49

SP - 1122

EP - 1124

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

IS - 6

ER -

Nucleophilic substitution of hydrogen in the reaction of 1,2,4-triazin-4-oxides with cyanamide

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this