TY - JOUR
T1 - Oil Media on Paper
T2 - Investigating the Interaction of Cold-Pressed Linseed Oil with Paper Supports with FTIR Analysis
AU - Banou, Penelope
AU - Boyatzis, Stamatis
AU - Choulis , Konstantinos
AU - Theodorakopoulos, Charis
AU - Alexopoulou, Athena
N1 - Funding information: Special Account for Research Grants of the University of West Attica (Greece) funded the publication of this article.
PY - 2023/6/2
Y1 - 2023/6/2
N2 - Previous works of the authors have presented the changes in the optical, mechanical, and chemical properties of the oiled areas of the supports that occur upon ageing due to oil-binder absorption in works of art on paper and printed material. In this framework, transmittance FTIR analysis has indicated that the presence of linseed oil induces the conditions to promote the deterioration of the oil-impregnated areas of the paper supports. However, the analysis of oil-impregnated mock-ups did not provide detailed information about the input of linseed oil formulations and the different types of paper support on the chemical changes that occur upon ageing. This work presents the results of ATR-FTIR and reflectance FTIR, which were used for compensating the previous results, proving indications on the effect of different materials (linseed oil formulations, and cellulosic and lignocellulosic papers) on the development of chemical changes, thus, on the condition of the oiled areas upon ageing. Although linseed oil formulations have a determining effect on the condition of the oiled areas of the support, the paper pulp content appears to have an input to the chemical changes that occur in the system of paper–linseed oil upon ageing. The results presented are more focused on the oil-impregnated mock-ups with cold-pressed linseed oil since results have indicated that this causes more extended changes upon ageing.
AB - Previous works of the authors have presented the changes in the optical, mechanical, and chemical properties of the oiled areas of the supports that occur upon ageing due to oil-binder absorption in works of art on paper and printed material. In this framework, transmittance FTIR analysis has indicated that the presence of linseed oil induces the conditions to promote the deterioration of the oil-impregnated areas of the paper supports. However, the analysis of oil-impregnated mock-ups did not provide detailed information about the input of linseed oil formulations and the different types of paper support on the chemical changes that occur upon ageing. This work presents the results of ATR-FTIR and reflectance FTIR, which were used for compensating the previous results, proving indications on the effect of different materials (linseed oil formulations, and cellulosic and lignocellulosic papers) on the development of chemical changes, thus, on the condition of the oiled areas upon ageing. Although linseed oil formulations have a determining effect on the condition of the oiled areas of the support, the paper pulp content appears to have an input to the chemical changes that occur in the system of paper–linseed oil upon ageing. The results presented are more focused on the oil-impregnated mock-ups with cold-pressed linseed oil since results have indicated that this causes more extended changes upon ageing.
KW - cold-pressed linseed oil
KW - alkaline-refined linseed oil
KW - stand oil
KW - pure cellulosic paper
KW - lignocellulosic paper
KW - ATR-FTIR
KW - reflectance FTIR
UR - http://www.scopus.com/inward/record.url?scp=85161511753&partnerID=8YFLogxK
U2 - 10.3390/polym15112567
DO - 10.3390/polym15112567
M3 - Article
SN - 2073-4360
VL - 15
JO - Polymers
JF - Polymers
IS - 11
M1 - 2567
ER -