Porous Bilayer Electrode-Guided Gas Diffusion for Enhanced CO 2 Electrochemical Reduction

Yucheng Wang, Hanhui Lei, Hang Xiang, Richard Fu, Chenxi Xu, Yinzhu Jiang, Ben Bin Xu*, Eileen Hao Yu*, Chao Gao*, Terence Liu*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

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Abstract

Comparing to the massive efforts in developing innovative catalyst materials system and technologies, structural design of cells has attracted less attentions on the road towards high performance electrochemical CO2 reduction reaction (eCO2RR). Here, we propose a hybrid gas diffusion electrode-based reaction cell by using highly porous carbon paper (CP) and graphene aerogels (GA), which is expected to offer directional diffusion of gas molecules onto the catalyst bed, to sustain a high performance in CO2 conversion. The above hypothesis has been supported by the experimental and simulation results, which show that the CP + GA combined configuration increases the Faraday efficiency (FE) from ~ 60% to over 94% towards carbon monoxide (CO) and formate production compared with a CP only cell with Cu2O as the catalyst. It also suppresses the undesirable side reaction - hydrogen evolution over 65 times than the conventional H-type cell (H-cell). By combining with advanced catalysts with high selectivity, a 100% FE of the cell with a high current density could be realised. The described strategy sheds an extra light on future development of eCO2RR with a structural design of cell enabled high CO2 conversion.
Original languageEnglish
Article number2100083
Number of pages8
JournalAdvanced Energy and Sustainability Research
Early online date7 Jun 2021
DOIs
Publication statusE-pub ahead of print - 7 Jun 2021

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