Precise Engineering of Octahedron-Induced Subcrystalline CoMoO4 Cathode Catalyst for High-Performance Li–Air Batteries

Huimin Zhou, Liang Guo, Runhao Zhang, Lei Xie, Yang Qiu, Guoliang Zhang, Zhanhu Guo, Biao Kong*, Feng Dang

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

25 Citations (Scopus)

Abstract

Lithium–air batteries (LABs) have attracted intense interest due to their ultrahigh energy density. However, the performance of LABs has to depend on modified electrolytes, gas selective film and Li anode protection. In this study, firstly it is reported that Mo-O octahedron induced subcrystalline scheelite CoMoO4 catalyst achieves a high performance LABs performance based only on the high catalytic activity in air. The subcrystalline CoMoO4 catalyst obtains a specific capacity of 12 000 mAh g−1, and ultralong cycle stability over 270 cycles at 1000 mA g−1 in ambient air. This study demonstrates an ultrastable crystal structure and surface conditions of the CoMoO4 catalyst toward a corrosive environment and complex air-involved reactions. A theoretical calculation further reveals that the polyhedral framework in the scheelite CoMoO4 can provide a highly stable catalytic surface for the OER/ORR reactions, furthermore, its repulsive nature toward H2O and CO2 can efficiently avoid side reactions and slow the corrosion of the Li anode in air. Moreover, the induced octahedron enhances the adsorption energies to O2 and LiO2, and accelerates the catalytic reactions in air. The present study provides a conceptual breakthrough to find highly active cathode catalysts for LABs.
Original languageEnglish
Article number2304154
JournalAdvanced Functional Materials
Volume33
Issue number41
Early online date8 Jun 2023
DOIs
Publication statusPublished - 9 Oct 2023

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