Preparation and cycloaddition reactions of novel heterocyclic mesomeric betaines

David Morgan, W. David Ollis, Stephen Stanforth

Research output: Contribution to journalArticlepeer-review

30 Citations (Scopus)

Abstract

The heterocyclic mesomeric betaines 6a-c reacted with dimethyl acetylenedicarboxylate and ethyl propiolate giving the 1,3-dipolar cycloaddition products 7a-c and 8a-c, respectively. With esters of maleic, fumaric, acrylic and methacrylic acids, mesomeric betaines 6a and 6b gave substituted tetralone derivatives.
Original languageEnglish
Pages (from-to)5523-5534
JournalTetrahedron
Volume56
Issue number30
DOIs
Publication statusPublished - Jul 2000

Keywords

  • 1
  • 3-dipoles
  • cycloadditions
  • mesomeric betaines
  • vinylketenes

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