Prominent removal of trace lead (II) ions from polluted water by terephthalic acid reformed Al/Zn metal organic nanoflakes

Junhua  Li; Lingshu  Gao; Junmao  Hong; Xiaofeng  Shi; Sifang  Kong; Jingyu  Wang; Hassan Algadi; Ben Bin Xu; Zhanhu Guo

doi:10.1016/j.partic.2023.02.020

Prominent removal of trace lead (II) ions from polluted water by terephthalic acid reformed Al/Zn metal organic nanoflakes

Junhua Li, Lingshu Gao, Junmao Hong, Xiaofeng Shi^*, Sifang Kong^*, Jingyu Wang, Hassan Algadi, Ben Bin Xu, Zhanhu Guo^*

^*Corresponding author for this work

Mechanical and Construction Engineering Department

Research output: Contribution to journal › Article › peer-review

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Abstract

Terephthalic acid reformed Al/Zn metal organic nanoflake was prepared and functionalized with triethylamine (T-AlZn). Without adding terephthalic acid, there was no product of metal organic nanoflake. T-AlZn has a remarkable performance in removing trace lead (II) ions (Pb2+). The adsorption equipoise with the removal rate ≥ 97% was reached within 35 min. The removal rates of T-AlZn for Pb2+ declined by only 16.73% after four regenerations. The adsorption of T-AlZn for Pb2+ follows the Langmuir isotherms model and pseudo-second-order dynamics model. The utmost adsorption competence was calculated as 215.27 mg·g-1. The T-AlZn adsorbent exhibits a bright prospect in the adsorption for Pb2+ and is a considerable candidate in the disposal of industrial sewage.

Original language	English
Pages (from-to)	81-88
Number of pages	8
Journal	Particuology
Volume	84
Early online date	17 Mar 2023
DOIs	https://doi.org/10.1016/j.partic.2023.02.020
Publication status	Published - 1 Jan 2024

Keywords

Metal organic complex
nanoflake
trace level
Pb2+
adsorption

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10.1016/j.partic.2023.02.020

main_text_finalAccepted author manuscript, 1.06 MBLicence: CC BY-NC-ND

Cite this

@article{137b1d0d474b48219cafb25867a9f78a,

title = "Prominent removal of trace lead (II) ions from polluted water by terephthalic acid reformed Al/Zn metal organic nanoflakes",

abstract = "Terephthalic acid reformed Al/Zn metal organic nanoflake was prepared and functionalized with triethylamine (T-AlZn). Without adding terephthalic acid, there was no product of metal organic nanoflake. T-AlZn has a remarkable performance in removing trace lead (II) ions (Pb2+). The adsorption equipoise with the removal rate ≥ 97% was reached within 35 min. The removal rates of T-AlZn for Pb2+ declined by only 16.73% after four regenerations. The adsorption of T-AlZn for Pb2+ follows the Langmuir isotherms model and pseudo-second-order dynamics model. The utmost adsorption competence was calculated as 215.27 mg·g-1. The T-AlZn adsorbent exhibits a bright prospect in the adsorption for Pb2+ and is a considerable candidate in the disposal of industrial sewage.",

keywords = "Metal organic complex, nanoflake, trace level, Pb2+, adsorption",

author = "Junhua Li and Lingshu Gao and Junmao Hong and Xiaofeng Shi and Sifang Kong and Jingyu Wang and Hassan Algadi and Xu, {Ben Bin} and Zhanhu Guo",

note = "Funding information: The supports from Shenzhen Science & Technology Project (grant No. KCXFZ20201221173612033) and School level technical research project of Shenzhen University (grant No. SZIIT2022KJ081) are highly appreciated.",

year = "2024",

month = jan,

day = "1",

doi = "10.1016/j.partic.2023.02.020",

language = "English",

volume = "84",

pages = "81--88",

journal = "Particuology",

issn = "1674-2001",

publisher = "Elsevier",

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TY - JOUR

T1 - Prominent removal of trace lead (II) ions from polluted water by terephthalic acid reformed Al/Zn metal organic nanoflakes

AU - Li, Junhua

AU - Gao, Lingshu

AU - Hong, Junmao

AU - Shi, Xiaofeng

AU - Kong, Sifang

AU - Wang, Jingyu

AU - Algadi, Hassan

AU - Xu, Ben Bin

AU - Guo, Zhanhu

N1 - Funding information: The supports from Shenzhen Science & Technology Project (grant No. KCXFZ20201221173612033) and School level technical research project of Shenzhen University (grant No. SZIIT2022KJ081) are highly appreciated.

PY - 2024/1/1

Y1 - 2024/1/1

N2 - Terephthalic acid reformed Al/Zn metal organic nanoflake was prepared and functionalized with triethylamine (T-AlZn). Without adding terephthalic acid, there was no product of metal organic nanoflake. T-AlZn has a remarkable performance in removing trace lead (II) ions (Pb2+). The adsorption equipoise with the removal rate ≥ 97% was reached within 35 min. The removal rates of T-AlZn for Pb2+ declined by only 16.73% after four regenerations. The adsorption of T-AlZn for Pb2+ follows the Langmuir isotherms model and pseudo-second-order dynamics model. The utmost adsorption competence was calculated as 215.27 mg·g-1. The T-AlZn adsorbent exhibits a bright prospect in the adsorption for Pb2+ and is a considerable candidate in the disposal of industrial sewage.

AB - Terephthalic acid reformed Al/Zn metal organic nanoflake was prepared and functionalized with triethylamine (T-AlZn). Without adding terephthalic acid, there was no product of metal organic nanoflake. T-AlZn has a remarkable performance in removing trace lead (II) ions (Pb2+). The adsorption equipoise with the removal rate ≥ 97% was reached within 35 min. The removal rates of T-AlZn for Pb2+ declined by only 16.73% after four regenerations. The adsorption of T-AlZn for Pb2+ follows the Langmuir isotherms model and pseudo-second-order dynamics model. The utmost adsorption competence was calculated as 215.27 mg·g-1. The T-AlZn adsorbent exhibits a bright prospect in the adsorption for Pb2+ and is a considerable candidate in the disposal of industrial sewage.

KW - Metal organic complex

KW - nanoflake

KW - trace level

KW - Pb2+

KW - adsorption

U2 - 10.1016/j.partic.2023.02.020

DO - 10.1016/j.partic.2023.02.020

M3 - Article

SN - 1674-2001

VL - 84

SP - 81

EP - 88

JO - Particuology

JF - Particuology

ER -