Rhenium-functionalized covalent organic framework photocatalyst for efficient CO                         
                        2
                                                  reduction under visible light

Shu Ying Li; Shuang Meng; Xiaoqin Zou; Mohamad El-Roz; Igor Telegeev; Oumaima Thili; Terence Xiaoteng Liu; Guangshan Zhu

doi:10.1016/j.micromeso.2019.05.026

Rhenium-functionalized covalent organic framework photocatalyst for efficient CO ₂ reduction under visible light

Shu Ying Li, Shuang Meng, Xiaoqin Zou^*, Mohamad El-Roz, Igor Telegeev, Oumaima Thili, Terence Xiaoteng Liu, Guangshan Zhu

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

103 Citations (Scopus)

44 Downloads (Pure)

Abstract

The conversion of carbon dioxide (CO ₂ ) into value-added chemicals under photochemical conditions has attracted increasing attention in recent years. One of the great challenges is to develop novel active catalysts under visible light irradiation with sustained lifetime and high activity. In this regard, herein, we report a highly efficient, stable and recyclable photocatalyst by embedding photoactive rhenium complex (Re(CO) ₅ Cl) into porous, crystalline, bipyridine-based covalent organic frameworks (COFs). The rhenium post-metallated COFs exhibits salient photocatalytic activity towards CO ₂ reduction into CO under visible light. The quantity of the CO produced on Re-functionalized COFs is twice higher than that produced on the famous Re(bpy)(CO) ₃ Cl (bpy = 2,2′-bipyridine) molecular photocatalyst under similar reaction conditions.

Original language	English
Pages (from-to)	195-201
Number of pages	7
Journal	Microporous and Mesoporous Materials
Volume	285
Early online date	14 May 2019
DOIs	https://doi.org/10.1016/j.micromeso.2019.05.026
Publication status	Published - 1 Sept 2019

Keywords

2D covalent organic framework
CO reduction
Molecular catalysis
Photocatalysis
Rhenium functionalization

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.micromeso.2019.05.026

Manuscript with note-zxqAccepted author manuscript, 1.37 MBLicence: CC BY-NC-ND

Cite this

Li, S. Y., Meng, S., Zou, X., El-Roz, M., Telegeev, I., Thili, O., Liu, T. X., & Zhu, G. (2019). Rhenium-functionalized covalent organic framework photocatalyst for efficient CO ₂ reduction under visible light. Microporous and Mesoporous Materials, 285, 195-201. https://doi.org/10.1016/j.micromeso.2019.05.026

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title = "Rhenium-functionalized covalent organic framework photocatalyst for efficient CO 2 reduction under visible light",

abstract = " The conversion of carbon dioxide (CO 2 ) into value-added chemicals under photochemical conditions has attracted increasing attention in recent years. One of the great challenges is to develop novel active catalysts under visible light irradiation with sustained lifetime and high activity. In this regard, herein, we report a highly efficient, stable and recyclable photocatalyst by embedding photoactive rhenium complex (Re(CO) 5 Cl) into porous, crystalline, bipyridine-based covalent organic frameworks (COFs). The rhenium post-metallated COFs exhibits salient photocatalytic activity towards CO 2 reduction into CO under visible light. The quantity of the CO produced on Re-functionalized COFs is twice higher than that produced on the famous Re(bpy)(CO) 3 Cl (bpy = 2,2′-bipyridine) molecular photocatalyst under similar reaction conditions. ",

keywords = "2D covalent organic framework, CO reduction, Molecular catalysis, Photocatalysis, Rhenium functionalization",

author = "Li, \{Shu Ying\} and Shuang Meng and Xiaoqin Zou and Mohamad El-Roz and Igor Telegeev and Oumaima Thili and Liu, \{Terence Xiaoteng\} and Guangshan Zhu",

year = "2019",

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doi = "10.1016/j.micromeso.2019.05.026",

language = "English",

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pages = "195--201",

journal = "Microporous and Mesoporous Materials",

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Li, SY, Meng, S, Zou, X, El-Roz, M, Telegeev, I, Thili, O, Liu, TX & Zhu, G 2019, 'Rhenium-functionalized covalent organic framework photocatalyst for efficient CO ₂ reduction under visible light', Microporous and Mesoporous Materials, vol. 285, pp. 195-201. https://doi.org/10.1016/j.micromeso.2019.05.026

Rhenium-functionalized covalent organic framework photocatalyst for efficient CO ₂ reduction under visible light. / Li, Shu Ying; Meng, Shuang; Zou, Xiaoqin et al.
In: Microporous and Mesoporous Materials, Vol. 285, 01.09.2019, p. 195-201.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Rhenium-functionalized covalent organic framework photocatalyst for efficient CO 2 reduction under visible light

AU - Li, Shu Ying

AU - Meng, Shuang

AU - Zou, Xiaoqin

AU - El-Roz, Mohamad

AU - Telegeev, Igor

AU - Thili, Oumaima

AU - Liu, Terence Xiaoteng

AU - Zhu, Guangshan

PY - 2019/9/1

Y1 - 2019/9/1

N2 - The conversion of carbon dioxide (CO 2 ) into value-added chemicals under photochemical conditions has attracted increasing attention in recent years. One of the great challenges is to develop novel active catalysts under visible light irradiation with sustained lifetime and high activity. In this regard, herein, we report a highly efficient, stable and recyclable photocatalyst by embedding photoactive rhenium complex (Re(CO) 5 Cl) into porous, crystalline, bipyridine-based covalent organic frameworks (COFs). The rhenium post-metallated COFs exhibits salient photocatalytic activity towards CO 2 reduction into CO under visible light. The quantity of the CO produced on Re-functionalized COFs is twice higher than that produced on the famous Re(bpy)(CO) 3 Cl (bpy = 2,2′-bipyridine) molecular photocatalyst under similar reaction conditions.

AB - The conversion of carbon dioxide (CO 2 ) into value-added chemicals under photochemical conditions has attracted increasing attention in recent years. One of the great challenges is to develop novel active catalysts under visible light irradiation with sustained lifetime and high activity. In this regard, herein, we report a highly efficient, stable and recyclable photocatalyst by embedding photoactive rhenium complex (Re(CO) 5 Cl) into porous, crystalline, bipyridine-based covalent organic frameworks (COFs). The rhenium post-metallated COFs exhibits salient photocatalytic activity towards CO 2 reduction into CO under visible light. The quantity of the CO produced on Re-functionalized COFs is twice higher than that produced on the famous Re(bpy)(CO) 3 Cl (bpy = 2,2′-bipyridine) molecular photocatalyst under similar reaction conditions.

KW - 2D covalent organic framework

KW - CO reduction

KW - Molecular catalysis

KW - Photocatalysis

KW - Rhenium functionalization

UR - https://www.scopus.com/pages/publications/85065657592

U2 - 10.1016/j.micromeso.2019.05.026

DO - 10.1016/j.micromeso.2019.05.026

M3 - Article

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VL - 285

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JO - Microporous and Mesoporous Materials

JF - Microporous and Mesoporous Materials

ER -

Li SY, Meng S, Zou X, El-Roz M, Telegeev I, Thili O et al. Rhenium-functionalized covalent organic framework photocatalyst for efficient CO ₂ reduction under visible light. Microporous and Mesoporous Materials. 2019 Sept 1;285:195-201. Epub 2019 May 14. doi: 10.1016/j.micromeso.2019.05.026