Rigidly linking cyclometallated Ir(iii) and Pt(ii) centres: an efficient approach to strongly absorbing and highly phosphorescent red emitters

Graeme Turnbull; Gareth Williams; Valery Kozhevnikov

doi:10.1039/c7cc00656j

Rigidly linking cyclometallated Ir(iii) and Pt(ii) centres: an efficient approach to strongly absorbing and highly phosphorescent red emitters

Graeme Turnbull, Gareth Williams, Valery Kozhevnikov

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35 Citations (Scopus)

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Abstract

The synthesis and photophysical properties of an unprecedented tetranuclear complex are described, in which a fac-tris-cyclometallated Ir(III) centre is rigidly connected to three cyclometallated Pt(II) centres. The complex absorbs strongly up to ∼600 nm and emits red light with unusually high efficiency.

Original language	English
Pages (from-to)	2729-2732
Journal	Chemical Communications
Volume	53
Issue number	18
DOIs	https://doi.org/10.1039/c7cc00656j
Publication status	Published - 4 Mar 2017

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10.1039/c7cc00656j

Final ManuscriptAccepted author manuscript, 1.11 MB
c7cc00656jFinal published version, 1.58 MBLicence: CC BY

Cite this

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title = "Rigidly linking cyclometallated Ir(iii) and Pt(ii) centres: an efficient approach to strongly absorbing and highly phosphorescent red emitters",

abstract = "The synthesis and photophysical properties of an unprecedented tetranuclear complex are described, in which a fac-tris-cyclometallated Ir(III) centre is rigidly connected to three cyclometallated Pt(II) centres. The complex absorbs strongly up to ∼600 nm and emits red light with unusually high efficiency.",

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AU - Turnbull, Graeme

AU - Williams, Gareth

AU - Kozhevnikov, Valery

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Y1 - 2017/3/4

N2 - The synthesis and photophysical properties of an unprecedented tetranuclear complex are described, in which a fac-tris-cyclometallated Ir(III) centre is rigidly connected to three cyclometallated Pt(II) centres. The complex absorbs strongly up to ∼600 nm and emits red light with unusually high efficiency.

AB - The synthesis and photophysical properties of an unprecedented tetranuclear complex are described, in which a fac-tris-cyclometallated Ir(III) centre is rigidly connected to three cyclometallated Pt(II) centres. The complex absorbs strongly up to ∼600 nm and emits red light with unusually high efficiency.

UR - https://www.scopus.com/pages/publications/85014206217

U2 - 10.1039/c7cc00656j

DO - 10.1039/c7cc00656j

M3 - Article

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VL - 53

SP - 2729

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JO - Chemical Communications

JF - Chemical Communications

IS - 18

ER -

Rigidly linking cyclometallated Ir(iii) and Pt(ii) centres: an efficient approach to strongly absorbing and highly phosphorescent red emitters

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