Selective extraction of organochlorine and organophosphorus pesticides using a combined solid phase extraction-supercritical fluid extraction approach

Ian Barnabas; John Dean; Steven Hitchen; Susan Owen

doi:10.1016/0003-2670(94)80021-9

Selective extraction of organochlorine and organophosphorus pesticides using a combined solid phase extraction-supercritical fluid extraction approach

Ian Barnabas, John Dean, Steven Hitchen, Susan Owen

Applied Sciences Department

Research output: Contribution to journal › Article › peer-review

47 Citations (Scopus)

Abstract

Supercritical fluid extraction (SFE) of pesticides has been investigated for the possibility of selective extraction between organochlorine (OCPs) and organophosphorus (OPPs) compounds. Three OCPs and OPPs were trapped onto a C18 Empore® extraction disk prior to SFE with CO2 only and methanol-modified CO2 at various pressures and constant temperature. The results indicate that OCPs can be quantitatively extracted using CO2 only whereas OPPs require a modifier for extraction.

Original language	English
Pages (from-to)	261-267
Journal	Analytica Chimica Acta
Volume	291
Issue number	3
DOIs	https://doi.org/10.1016/0003-2670(94)80021-9
Publication status	Published - Jun 1994

Keywords

Gas chromatography-mass spectrometry
Pesticides
Selective extraction
Supercritical fluid extraction

Access to Document

10.1016/0003-2670(94)80021-9

Cite this

@article{c7e7b1b15bec43049aef7c9a99c192eb,

title = "Selective extraction of organochlorine and organophosphorus pesticides using a combined solid phase extraction-supercritical fluid extraction approach",

abstract = "Supercritical fluid extraction (SFE) of pesticides has been investigated for the possibility of selective extraction between organochlorine (OCPs) and organophosphorus (OPPs) compounds. Three OCPs and OPPs were trapped onto a C18 Empore{\textregistered} extraction disk prior to SFE with CO2 only and methanol-modified CO2 at various pressures and constant temperature. The results indicate that OCPs can be quantitatively extracted using CO2 only whereas OPPs require a modifier for extraction.",

keywords = "Gas chromatography-mass spectrometry, Pesticides, Selective extraction, Supercritical fluid extraction",

author = "Ian Barnabas and John Dean and Steven Hitchen and Susan Owen",

year = "1994",

month = jun,

doi = "10.1016/0003-2670(94)80021-9",

language = "English",

volume = "291",

pages = "261--267",

journal = "Analytica Chimica Acta",

issn = "0003-2670",

publisher = "Elsevier",

number = "3",

}

TY - JOUR

T1 - Selective extraction of organochlorine and organophosphorus pesticides using a combined solid phase extraction-supercritical fluid extraction approach

AU - Barnabas, Ian

AU - Dean, John

AU - Hitchen, Steven

AU - Owen, Susan

PY - 1994/6

Y1 - 1994/6

N2 - Supercritical fluid extraction (SFE) of pesticides has been investigated for the possibility of selective extraction between organochlorine (OCPs) and organophosphorus (OPPs) compounds. Three OCPs and OPPs were trapped onto a C18 Empore® extraction disk prior to SFE with CO2 only and methanol-modified CO2 at various pressures and constant temperature. The results indicate that OCPs can be quantitatively extracted using CO2 only whereas OPPs require a modifier for extraction.

AB - Supercritical fluid extraction (SFE) of pesticides has been investigated for the possibility of selective extraction between organochlorine (OCPs) and organophosphorus (OPPs) compounds. Three OCPs and OPPs were trapped onto a C18 Empore® extraction disk prior to SFE with CO2 only and methanol-modified CO2 at various pressures and constant temperature. The results indicate that OCPs can be quantitatively extracted using CO2 only whereas OPPs require a modifier for extraction.

KW - Gas chromatography-mass spectrometry

KW - Pesticides

KW - Selective extraction

KW - Supercritical fluid extraction

U2 - 10.1016/0003-2670(94)80021-9

DO - 10.1016/0003-2670(94)80021-9

M3 - Article

SN - 0003-2670

VL - 291

SP - 261

EP - 267

JO - Analytica Chimica Acta

JF - Analytica Chimica Acta

IS - 3

ER -

Selective extraction of organochlorine and organophosphorus pesticides using a combined solid phase extraction-supercritical fluid extraction approach

Abstract

Keywords

Access to Document

Fingerprint

Cite this