Significantly Stabilizing Hydrogen Evolution Reaction Induced by Nb-Doping Pt/Co(OH)2 Nanosheets

Yakun Tian, Ming Wen*, Aijian Huang, Qingsheng Wu, Zhiguo Wang, Quanjing Zhu, Tao Zhou, Yongqing (Richard) Fu

*Corresponding author for this work

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6 Citations (Scopus)


High stability and efficiency of electrocatalysts are crucial for hydrogen evolution reaction (HER) toward water splitting in an alkaline media. Herein, a novel nano-Pt/Nb-doped Co(OH)2 (Pt/NbCo(OH)2) nanosheet is designed and synthesized using water-bath treatment and solvothermal reduction approaches. With nano-Pt uniformly anchored onto NbCo(OH)2 nanosheet, the synthesized Pt/NbCo(OH)2 shows outstanding electrocatalytic performances for alkaline HER, achieving a high stability for at least 33 h, a high mass activity of 0.65 mA µg−1 Pt, and a good catalytic activity with a low overpotential of 112 mV at 10 mA cm−2. Both experimental and theoretical results prove that Nb-doping significantly optimizes the hydrogen adsorption free energy to accelerate the Heyrovsky step for HER, and boosts the adsorption of H2O, which further enhances the water activation. This study provides a new design methodology for the Nb-doped electrocatalysts in an alkaline HER field by facile and green way.
Original languageEnglish
Article number2207569
Number of pages11
Issue number20
Early online date24 Feb 2023
Publication statusPublished - 17 May 2023

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