Symmetries and criticality of generalised van der Waals models

Francesco Giglio*, Giulio Landolfi, Luigi Martina, Antonio Moro

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review

    4 Citations (Scopus)
    76 Downloads (Pure)

    Abstract

    We consider a family of thermodynamic models such that the energy density can be expressed as an asymptotic expansion in the scale formal parameter and whose terms are suitable functions of the volume density. We examine the possibility to construct solutions for the Maxwell thermodynamic relations relying on their symmetry properties and deduce the critical properties implied in terms of the the dynamics of coexistence curves in the space of thermodynamic variables.
    Original languageEnglish
    Article number405701
    Number of pages10
    JournalJournal of Physics A: Mathematical and Theoretical
    Volume54
    Issue number40
    Early online date9 Sept 2021
    DOIs
    Publication statusPublished - 8 Oct 2021

    Keywords

    • Critical points and phase transitions
    • Shock waves
    • Symmetries of differential equations
    • Van der Waals type systems

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