Synthesis and electro-polymerisation of a novel heteropentalene mesomeric betaine: preparation of a novel low band-gap conjugated polymer

Saadeldin Elmasly; Alexander Gehre; Peter Skabara; Stephen Stanforth; Filipe Vilela

doi:10.1016/j.tetlet.2010.11.109

Synthesis and electro-polymerisation of a novel heteropentalene mesomeric betaine: preparation of a novel low band-gap conjugated polymer

Saadeldin Elmasly, Alexander Gehre, Peter Skabara, Stephen Stanforth, Filipe Vilela

Applied Sciences Department

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The 3,4-ethylenedioxythiophene (EDOT)-containing heteropentalene mesomeric betaine 9 has been prepared and electro-polymerised. When coated onto an indium tin oxide (ITO) covered glass slide the optical band-gap of the polymer was determined as 1.75 eV.

Original language	English
Pages (from-to)	526-529
Journal	Tetrahedron Letters
Volume	52
Issue number	4
DOIs	https://doi.org/10.1016/j.tetlet.2010.11.109
Publication status	Published - 26 Jan 2011

Keywords

Low band-gap polymers
electro-polymerisation
heteropentalene mesomeric betaines
3
4-Ethylenedioxythiophene
polythiophenes

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10.1016/j.tetlet.2010.11.109

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title = "Synthesis and electro-polymerisation of a novel heteropentalene mesomeric betaine: preparation of a novel low band-gap conjugated polymer",

abstract = "The 3,4-ethylenedioxythiophene (EDOT)-containing heteropentalene mesomeric betaine 9 has been prepared and electro-polymerised. When coated onto an indium tin oxide (ITO) covered glass slide the optical band-gap of the polymer was determined as 1.75 eV.",

keywords = "Low band-gap polymers, electro-polymerisation, heteropentalene mesomeric betaines, 3, 4-Ethylenedioxythiophene, polythiophenes",

author = "Saadeldin Elmasly and Alexander Gehre and Peter Skabara and Stephen Stanforth and Filipe Vilela",

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T1 - Synthesis and electro-polymerisation of a novel heteropentalene mesomeric betaine: preparation of a novel low band-gap conjugated polymer

AU - Elmasly, Saadeldin

AU - Gehre, Alexander

AU - Skabara, Peter

AU - Stanforth, Stephen

AU - Vilela, Filipe

PY - 2011/1/26

Y1 - 2011/1/26

N2 - The 3,4-ethylenedioxythiophene (EDOT)-containing heteropentalene mesomeric betaine 9 has been prepared and electro-polymerised. When coated onto an indium tin oxide (ITO) covered glass slide the optical band-gap of the polymer was determined as 1.75 eV.

AB - The 3,4-ethylenedioxythiophene (EDOT)-containing heteropentalene mesomeric betaine 9 has been prepared and electro-polymerised. When coated onto an indium tin oxide (ITO) covered glass slide the optical band-gap of the polymer was determined as 1.75 eV.

KW - Low band-gap polymers

KW - electro-polymerisation

KW - heteropentalene mesomeric betaines

KW - 3

KW - 4-Ethylenedioxythiophene

KW - polythiophenes

U2 - 10.1016/j.tetlet.2010.11.109

DO - 10.1016/j.tetlet.2010.11.109

M3 - Article

SN - 0040-4039

VL - 52

SP - 526

EP - 529

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 4

ER -

Synthesis and electro-polymerisation of a novel heteropentalene mesomeric betaine: preparation of a novel low band-gap conjugated polymer

Abstract

Keywords

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