Synthesis of 2,2′-bipyridyl derivatives using aza Diels-Alder methodology

Stephen Stanforth; Brian Tarbit; Michael Watson

doi:10.1016/S0040-4039(02)02670-9

Synthesis of 2,2′-bipyridyl derivatives using aza Diels-Alder methodology

Stephen Stanforth, Brian Tarbit, Michael Watson

Applied Sciences Department

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

Amidrazone 1 and the tricarbonyl derivatives 2a-c gave the triazines 3a-c, respectively, which reacted with 2,5-norbornadiene 4 in boiling ethanol yielding the corresponding novel 2,2′-bipyridines 5a-c in good yield. Triazine 6 gave the 2,2′-bipyridyl derivative 7 (65%) with compound 4 in 1,2-dichlorobenzene at 140°C. © 2003 Elsevier Science Ltd. All rights reserved.

Original language	English
Pages (from-to)	693-694
Journal	Tetrahedron Letters
Volume	44
Issue number	4
DOIs	https://doi.org/10.1016/S0040-4039(02)02670-9
Publication status	Published - Jan 2003

Keywords

1
2
4-triazines
2′-bipyridyls
Aza Diels-Alder reaction

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10.1016/S0040-4039(02)02670-9

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title = "Synthesis of 2,2′-bipyridyl derivatives using aza Diels-Alder methodology",

abstract = "Amidrazone 1 and the tricarbonyl derivatives 2a-c gave the triazines 3a-c, respectively, which reacted with 2,5-norbornadiene 4 in boiling ethanol yielding the corresponding novel 2,2′-bipyridines 5a-c in good yield. Triazine 6 gave the 2,2′-bipyridyl derivative 7 (65%) with compound 4 in 1,2-dichlorobenzene at 140°C. {\textcopyright} 2003 Elsevier Science Ltd. All rights reserved.",

keywords = "1, 2, 4-triazines, 2′-bipyridyls, Aza Diels-Alder reaction",

author = "Stephen Stanforth and Brian Tarbit and Michael Watson",

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T1 - Synthesis of 2,2′-bipyridyl derivatives using aza Diels-Alder methodology

AU - Stanforth, Stephen

AU - Tarbit, Brian

AU - Watson, Michael

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N2 - Amidrazone 1 and the tricarbonyl derivatives 2a-c gave the triazines 3a-c, respectively, which reacted with 2,5-norbornadiene 4 in boiling ethanol yielding the corresponding novel 2,2′-bipyridines 5a-c in good yield. Triazine 6 gave the 2,2′-bipyridyl derivative 7 (65%) with compound 4 in 1,2-dichlorobenzene at 140°C. © 2003 Elsevier Science Ltd. All rights reserved.

AB - Amidrazone 1 and the tricarbonyl derivatives 2a-c gave the triazines 3a-c, respectively, which reacted with 2,5-norbornadiene 4 in boiling ethanol yielding the corresponding novel 2,2′-bipyridines 5a-c in good yield. Triazine 6 gave the 2,2′-bipyridyl derivative 7 (65%) with compound 4 in 1,2-dichlorobenzene at 140°C. © 2003 Elsevier Science Ltd. All rights reserved.

KW - 1

KW - 2

KW - 4-triazines

KW - 2′-bipyridyls

KW - Aza Diels-Alder reaction

U2 - 10.1016/S0040-4039(02)02670-9

DO - 10.1016/S0040-4039(02)02670-9

M3 - Article

SN - 0040-4039

VL - 44

SP - 693

EP - 694

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 4

ER -

Synthesis of 2,2′-bipyridyl derivatives using aza Diels-Alder methodology

Abstract

Keywords

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