Synthesis of di-μ-oxo manganese(III/IV) complexes as functional models of L. Plantarum pseudo-catalase: Influence of electronic and steric factors; catalysis and kinetics of hydrogen peroxide disproportionation

Michel Delroisse, Alain Rabion, Françoise Chardac, David Tétard, Jean Baptiste Verlhac*, Laurent Fraisse, Jean Louis Séris

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

29 Citations (Scopus)

Abstract

Di-μ-oxo dimanganese(III/IV) complexes are efficient catalysts for H2O2 disproportionation in neutral aqueous medium; the activity can be correlated to the electron density on the metal and the accessibility of the catalytic site.

Original languageEnglish
Pages (from-to)949-950
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number9
DOIs
Publication statusPublished - 1995
Externally publishedYes

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